Get 20M+ Full-Text Papers For Less Than $1.50/day. Start a 14-Day Trial for You or Your Team.

Learn More →

A Ternary Zn−Al−Ir Hydrotalcite‐Like Compound Exhibiting High Efficiency and Recyclability as a Water Oxidation Catalyst

A Ternary Zn−Al−Ir Hydrotalcite‐Like Compound Exhibiting High Efficiency and Recyclability as a... Herein it is shown that hydrotalcite‐like compounds (HTlcs), doped with a suitably reactive metal, can efficiently act as water oxidation catalysts. As a case study, a ternary HTlc of formula [Zn0.667Al0.306Ir0.027(OH)2]Cl0.333⋅0.6 H2O, in which iridium is homogeneously distributed into the octahedral sites of brucite‐type sheets, was prepared and tested as a heterogeneous water oxidation catalyst, using NaIO4 as a sacrificial oxidant. This HTlc showed excellent performance in terms of turnover frequency (up to 113 min−1), turnover number (>11 900), stability and recyclability. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png ChemPlusChem Wiley

A Ternary Zn−Al−Ir Hydrotalcite‐Like Compound Exhibiting High Efficiency and Recyclability as a Water Oxidation Catalyst

Loading next page...
 
/lp/wiley/a-ternary-zn-al-ir-hydrotalcite-like-compound-exhibiting-high-JhVHOxlsr0

References (50)

Publisher
Wiley
Copyright
© 2016 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim
ISSN
2192-6506
eISSN
2192-6506
DOI
10.1002/cplu.201600087
Publisher site
See Article on Publisher Site

Abstract

Herein it is shown that hydrotalcite‐like compounds (HTlcs), doped with a suitably reactive metal, can efficiently act as water oxidation catalysts. As a case study, a ternary HTlc of formula [Zn0.667Al0.306Ir0.027(OH)2]Cl0.333⋅0.6 H2O, in which iridium is homogeneously distributed into the octahedral sites of brucite‐type sheets, was prepared and tested as a heterogeneous water oxidation catalyst, using NaIO4 as a sacrificial oxidant. This HTlc showed excellent performance in terms of turnover frequency (up to 113 min−1), turnover number (>11 900), stability and recyclability.

Journal

ChemPlusChemWiley

Published: Oct 1, 2016

Keywords: ; ; ; ;

There are no references for this article.