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A Ternary Fe1−xS@Porous Carbon Nanowires/Reduced Graphene Oxide Hybrid Film Electrode with Superior Volumetric and Gravimetric Capacities for Flexible Sodium Ion Batteries

A Ternary Fe1−xS@Porous Carbon Nanowires/Reduced Graphene Oxide Hybrid Film Electrode with... Smart construction of ultraflexible electrodes with superior gravimetric and volumetric capacities is still challenging yet significant for sodium ion batteries (SIBs) toward wearable electronic devices. Herein, a hybrid film made of hierarchical Fe1−xS‐filled porous carbon nanowires/reduced graphene oxide (Fe1−xS@PCNWs/rGO) is synthesized through a facile assembly and sulfuration strategy. The resultant hybrid paper exhibits high flexibility and structural stability. The multidimensional paper architecture possesses several advantages, including rendering an efficient electron/ion transport network, buffering the volume expansion of Fe1−xS nanoparticles, mitigating the dissolution of polysulfides, and enabling superior kinetics toward efficient sodium storage. When evaluated as a self‐supporting anode for SIBs, the Fe1−xS@PCNWs/rGO paper electrode exhibits remarkable reversible capacities of 573–89 mAh g−1 over 100 consecutive cycles at 0.1 A g−1 with areal mass loadings of 0.9–11.2 mg cm−2 and high volumetric capacities of 424–180 mAh cm−3 in the current density range of 0.2–5 A g−1. More competitively, a SIB based on this flexible Fe1−xS@PCNWs/rGO anode demonstrates outstanding electrochemical properties, thus highlighting its enormous potential in versatile flexible and wearable applications. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Advanced Energy Materials Wiley

A Ternary Fe1−xS@Porous Carbon Nanowires/Reduced Graphene Oxide Hybrid Film Electrode with Superior Volumetric and Gravimetric Capacities for Flexible Sodium Ion Batteries

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Publisher
Wiley
Copyright
"© 2019 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim"
ISSN
1614-6832
eISSN
1614-6840
DOI
10.1002/aenm.201803052
Publisher site
See Article on Publisher Site

Abstract

Smart construction of ultraflexible electrodes with superior gravimetric and volumetric capacities is still challenging yet significant for sodium ion batteries (SIBs) toward wearable electronic devices. Herein, a hybrid film made of hierarchical Fe1−xS‐filled porous carbon nanowires/reduced graphene oxide (Fe1−xS@PCNWs/rGO) is synthesized through a facile assembly and sulfuration strategy. The resultant hybrid paper exhibits high flexibility and structural stability. The multidimensional paper architecture possesses several advantages, including rendering an efficient electron/ion transport network, buffering the volume expansion of Fe1−xS nanoparticles, mitigating the dissolution of polysulfides, and enabling superior kinetics toward efficient sodium storage. When evaluated as a self‐supporting anode for SIBs, the Fe1−xS@PCNWs/rGO paper electrode exhibits remarkable reversible capacities of 573–89 mAh g−1 over 100 consecutive cycles at 0.1 A g−1 with areal mass loadings of 0.9–11.2 mg cm−2 and high volumetric capacities of 424–180 mAh cm−3 in the current density range of 0.2–5 A g−1. More competitively, a SIB based on this flexible Fe1−xS@PCNWs/rGO anode demonstrates outstanding electrochemical properties, thus highlighting its enormous potential in versatile flexible and wearable applications.

Journal

Advanced Energy Materials – Wiley

Published: Mar 1, 2019

Keywords: ; ; ;

References