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- Publisher
- Wiley
- Copyright
- © 2017 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim
- ISSN
- 2193-5807
- eISSN
- 2193-5815
- DOI
- 10.1002/ajoc.201700049
- Publisher site
- See Article on Publisher Site
Abstract
A copper‐catalyzed highly diastereoselective multicomponent reaction (MCR) of α‐amino aldehydes, dibenzylamine and various alkynes leading to propargyl syn 1,2‐diamines has been established. The methodology has been further supported by the total synthesis of (+)‐ and (−)‐epiquinamides from A3‐coupled adducts derived from l‐ and d‐pipecolic acids, respectively, in overall yields of 31 %.
Journal
Asian Journal of Organic Chemistry – Wiley
Published: May 1, 2017
Keywords: ; ; ; ;