Access the full text.
Sign up today, get DeepDyve free for 14 days.
Jia-Li Xiao, Shu-ying Sun, Xingfu Song, Ping Li, Jianguo Yu (2015)
Lithium ion recovery from brine using granulated polyacrylamide–MnO2 ion-sieveChemical Engineering Journal, 279
Jaehan Lee, Seungho Yu, Choonsoo Kim, Y. Sung, Jeyong Yoon (2013)
Highly selective lithium recovery from brine using a λ-MnO2-Ag battery.Physical chemistry chemical physics : PCCP, 15 20
K. Babu, P. Kumar, O. Hussain (2012)
Microstructural and electrochemical properties of rf-sputtered LiMn2O4 thin film cathodesApplied Nanoscience, 2
Xin Xu, Xin Xu, You Zhou, M. Fan, Z. Lv, Yang Tang, Yanzhi Sun, Yongmei Chen, P. Wan (2017)
Lithium adsorption performance of a three-dimensional porous H2TiO3-type lithium ion-sieve in strong alkaline Bayer liquorRSC Advances, 7
Shu-ying Sun, Jia-Li Xiao, Jin Wang, Xingfu Song, Jianguo Yu (2014)
Synthesis and Adsorption Properties of Li1.6Mn1.6O4 by a Combination of Redox Precipitation and Solid-Phase ReactionIndustrial & Engineering Chemistry Research, 53
V. Luong, Dongjuan Kang, J. An, D. Dao, M. Kim, T. Tran (2014)
Iron sulphate roasting for extraction of lithium from lepidoliteHydrometallurgy, 141
R. Chitrakar, H. Kanoh, Y. Miyai, K. Ooi (2000)
A New Type of Manganese Oxide (MnO2·0.5H2O) Derived from Li1.6Mn1.6O4 and Its Lithium Ion-Sieve PropertiesChemistry of Materials, 12
Yongyao Xia, M. Yoshio (1996)
An Investigation of Lithium Ion Insertion into Spinel Structure Li‐Mn‐O CompoundsJournal of The Electrochemical Society, 143
E. Carella, T. Hernández (2012)
Ceramics for fusion reactors: The role of the lithium orthosilicate as breederPhysica B-condensed Matter, 407
M. Fehse, R. Trócoli, E. Ventosa, E. Hernández, A. Sepúlveda, Á. Morata, A. Tarancón (2017)
Ultrafast Dischargeable LiMn2O4 Thin-Film Electrodes with Pseudocapacitive Properties for Microbatteries.ACS applied materials & interfaces, 9 6
R. Fikry, R. El-Adly, N. Ismail, A. El-Tabei, Hend Al-Aidy (2013)
Some azine and azole derivatives as antioxidant additives for lithium lubricating greaseEgyptian Journal of Petroleum, 22
H. Xia, Qiuying Xia, Binghui Lin, Junwu Zhu, J. Seo, Y. Meng (2016)
Self-standing porous LiMn2O4 nanowall arrays as promising cathodes for advanced 3D microbatteries and flexible lithium-ion batteriesNano Energy, 22
K. Yanagase, T. Yoshinaga, K. Kawano, Toshikazu Matsuoka (1983)
The recovery of lithium from geothermal water in the Hatchobaru area of Kyushu, Japan.Bulletin of the Chemical Society of Japan, 56
K. Ooi, Y. Miyai, S. Katoh, H. Maeda, M. Abe (1990)
Analysis of pH titration data in a .lambda.-manganese dioxide + lithium hydroxide system on the basis of redox mechanismLangmuir, 6
Qin-Hui Zhang, Shu-ying Sun, Shaokang Li, Hao Jiang, Jianguo Yu (2007)
Adsorption of lithium ions on novel nanocrystal MnO2Chemical Engineering Science, 62
M. Fehse, R. Trócoli, E. Hernández, E. Ventosa, A. Sepúlveda, Á. Morata, A. Tarancón (2018)
An innovative multi-layer pulsed laser deposition approach for LiMn2O4 thin film cathodesThin Solid Films, 648
Dantong Li, Jiawen Guo, Xiaoming Wang, Shuaishuai Zhang, L. He (2016)
Effects of crystal size on the mechanical properties of a lithium disilicate glass-ceramicMaterials Science and Engineering A-structural Materials Properties Microstructure and Processing, 669
J. Epstein, E. Feist, J. Zmora, Y. Marcus (1981)
Extraction of lithium from the dead seaHydrometallurgy, 6
Weiping Tang, H. Kanoh, K. Ooi (1999)
Lithium Ion Extraction from Orthorhombic LiMnO2in Ammonium Peroxodisulfate SolutionsIEEE Journal of Solid-state Circuits, 142
R. Trócoli, Alberto Battistel, F. Mantia (2015)
Nickel hexacyanoferrate as suitable alternative to Ag for electrochemical lithium recovery.ChemSusChem, 8 15
Y. Miyai, K. Ooi, S. Katoh (1988)
Recovery of Lithium from Seawater Using a New Type of Ion-Sieve Adsorbent Based on MgMn2O4Separation Science and Technology, 23
D. Dembińska-Krajewska, J. Rybakowski (2015)
Psychotropic drugs and personality changes: A case of lithiumPharmacological Reports, 67
R. Trócoli, Ghoncheh Bidhendi, F. Mantia (2016)
Lithium recovery by means of electrochemical ion pumping: a comparison between salt capturing and selective exchangeJournal of Physics: Condensed Matter, 28
Xin Xu, Yongmei Chen, P. Wan, K. Gasem, Kaiying Wang, T. He, H. Adidharma, M. Fan (2016)
Extraction of lithium with functionalized lithium ion-sievesProgress in Materials Science, 84
R. Trócoli, C. Erinmwingbovo, F. Mantia (2017)
Optimized Lithium Recovery from Brines by using an Electrochemical Ion‐Pumping Process Based on λ‐MnO2 and Nickel Hexacyanoferrate, 4
Camille Grosjean, Pamela Miranda, M. Perrin, P. Poggi (2012)
Assessment of world lithium resources and consequences of their geographic distribution on the expected development of the electric vehicle industryRenewable & Sustainable Energy Reviews, 16
R. Trócoli, Á. Morata, M. Fehse, M. Stchakovsky, A. Sepúlveda, A. Tarancón (2017)
High Specific Power Dual-Metal-Ion Rechargeable Microbatteries Based on LiMn2O4 and Zinc for Miniaturized Applications.ACS applied materials & interfaces, 9 38
K. Kanamura, Hidetoshi Naito, T. Yao, Z. Takehara (1996)
Structural change of the LiMn2O4 spinel structure induced by extraction of lithiumJournal of Materials Chemistry, 6
Meng Zhao, Z. Ji, Yongguang Zhang, Zhikun Guo, Yingying Zhao, Jie Liu, Junsheng Yuan (2017)
Study on lithium extraction from brines based on LiMn2O4/Li1-xMn2O4 by electrochemical methodElectrochimica Acta, 252
R. Trócoli, A. Dushina, S. Borhani-Haghighi, A. Ludwig, F. Mantia (2018)
Effect of Pt and Au current collector in LiMn2O4 thin film for micro-batteriesNanotechnology, 29
Seoni Kim, Jaehan Lee, Jin Kang, Kyusik Jo, Seonghwan Kim, Y. Sung, Jeyong Yoon (2015)
Lithium recovery from brine using a λ-MnO2/activated carbon hybrid supercapacitor system.Chemosphere, 125
Xiuqiang Xie, D. Su, Bing Sun, Jinqiang Zhang, Chengyin Wang, Guoxiu Wang (2014)
Synthesis of single-crystalline spinel LiMn2 O4 Nanorods for lithium-ion batteries with high rate capability and long cycle life.Chemistry, 20 51
Taegong Ryu, Ju-Kyung Shin, Dong-Hee Lee, J. Ryu, In-Su Park, Hye-Jin Hong, Y. Huh, Byoung-Gyu Kim, K. Chung (2015)
Development of multi-stage column for lithium recovery from an aqueous solutionHydrometallurgy, 157
S. Borhani-Haghighi, C. Khare, R. Trócoli, A. Dushina, M. Kieschnick, F. Lamantia, A. Ludwig (2016)
Synthesis of nanostructured LiMn2O4 thin films by glancing angle deposition for Li-ion battery applicationsNanotechnology, 27
F. Marchini, D. Rubi, M. Pozo, F. Williams, E. Calvo (2016)
Surface Chemistry and Lithium-Ion Exchange in LiMn2O4 for the Electrochemical Selective Extraction of LiCl from Natural Salt Lake BrinesJournal of Physical Chemistry C, 120
S. Bach, J. Farcy, J. Pereira‐Ramos (1998)
An electrochemical investigation of Li intercalation in the sol-gel LiMn2O4 spinel oxideSolid State Ionics, 110
M. Mirkin, Hong-Xu Yang, A. Bard (1992)
Borohydride Oxidation at a Gold ElectrodeJournal of The Electrochemical Society, 139
H. Kanoh, K. Ooi, Y. Miyai, S. Katoh (1993)
Electrochemical Recovery of Lithium Ions in the Aqueous PhaseSeparation Science and Technology, 28
S. Mukerjee, T. Thurston, N. Jisrawi, X. Yang, J. Mcbreen, M. Daroux, X. Xing (1998)
Structural evolution of Li{sub x}Mn{sub 2}O{sub 4} in lithium-ion battery cells measured in situ using synchrotron X-ray diffraction techniquesJournal of The Electrochemical Society, 145
Bao-sheng Liu, Zhen-bo Wang, Yin Zhang, Fu‐da Yu, Yuan Xue, Ke Ke, Fangfei Li (2015)
Preparation of submicrocrystal LiMn2O4 used Mn3O4 as precursor and its electrochemical performance for lithium ion batteryJournal of Alloys and Compounds, 622
R. Trócoli, Alberto Battistel, F. Mantia (2014)
Selectivity of a lithium-recovery process based on LiFePO4.Chemistry, 20 32
M. Hannan, M. Lipu, A. Hussain, A. Mohamed (2017)
A review of lithium-ion battery state of charge estimation and management system in electric vehicle applications: Challenges and recommendationsRenewable & Sustainable Energy Reviews, 78
F. Seeley, W. Baldwin (1976)
Extraction of lithium from neutral salt solutions with fluorinated β-diketones☆Journal of Inorganic and Nuclear Chemistry, 38
Q. Qu, L. Fu, X. Zhan, D. Samuelis, J. Maier, Lei Li, S. Tian, Zhaohui Li, Yuping Wu (2011)
Porous LiMn2O4 as cathode material with high power and excellent cycling for aqueous rechargeable lithium batteriesEnergy and Environmental Science, 4
A. Eftekhari (2001)
Electrochemical behavior of thin-film LiMn2O4 electrode in aqueous mediaElectrochimica Acta, 47
K. Ooi, Y. Miyai, S. Katoh, H. Maeda, M. Abe (1989)
Topotactic lithium(1+) insertion to .lambda.-manganese dioxide in the aqueous phaseLangmuir, 5
Lithium recovery from an aqueous resource was accelerated by electrochemically driving the transformation of MnIV/MnIII with a spinel λ‐MnO2 film electrode. A λ‐MnO2 electrode without binders or conductive additives is preferred for achieving a large capacity at high current density and long‐term cycling capability. In this study, a film of Mn(OH)2 was first deposited on the surface of Pt or graphite substrates owing to alkalization near the cathode, then it was oxidized to a Mn3O4 film by air, followed by being hydrothermally lithiated to LiMn2O4 spinel and, finally, it was turned into the λ‐MnO2 film electrode through potentiostatic delithiation. The results show that the charging/discharging electric capacity of the fabricated λ‐MnO2 film electrode was up to ≈100 mAh g−1 at a current density of 50 mA g−1 in 30 mm Li+ aqueous solution, twice that of the λ‐MnO2 powder electrode. Also, 82.3 % lithium capacity remained after 100 cycles of an electrochemically assisted lithium recovery process, indicating high availability and good stability of the λ‐MnO2 spinel on the electrode. The energy consumption for each cycle is estimated to be approximately 1.55±0.09 J, implying that only 4.14 Wh is required for recovery of one mole of lithium ions by this method.
ChemPlusChem – Wiley
Published: Jan 1, 2018
Keywords: ; ; ; ;
Read and print from thousands of top scholarly journals.
Already have an account? Log in
Bookmark this article. You can see your Bookmarks on your DeepDyve Library.
To save an article, log in first, or sign up for a DeepDyve account if you don’t already have one.
Copy and paste the desired citation format or use the link below to download a file formatted for EndNote
Access the full text.
Sign up today, get DeepDyve free for 14 days.
All DeepDyve websites use cookies to improve your online experience. They were placed on your computer when you launched this website. You can change your cookie settings through your browser.