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A Redox Switchable Dihydrobenzo[b]pyrazine Push‐Pull System

A Redox Switchable Dihydrobenzo[b]pyrazine Push‐Pull System The synthesis and spectroscopic properties of a dissymmetrically core‐extended naphthalene diimides derived from o‐phenylenediamine and cyanoethene dithiolate were explored. The push‐pull nature of the peripheral substituents allows these naphthalene diimide dyes and their progenitors to display interesting photophysical and electrochemical properties, with the target system acting as a highly reversible and quantitative molecular switch with clear absorption and emission readouts based on chemical oxidation and reduction processes. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Asian Journal of Organic Chemistry Wiley

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References (56)

Publisher
Wiley
Copyright
Copyright © 2014 Wiley Subscription Services, Inc., A Wiley Company
ISSN
2193-5807
eISSN
2193-5815
DOI
10.1002/ajoc.201402015
Publisher site
See Article on Publisher Site

Abstract

The synthesis and spectroscopic properties of a dissymmetrically core‐extended naphthalene diimides derived from o‐phenylenediamine and cyanoethene dithiolate were explored. The push‐pull nature of the peripheral substituents allows these naphthalene diimide dyes and their progenitors to display interesting photophysical and electrochemical properties, with the target system acting as a highly reversible and quantitative molecular switch with clear absorption and emission readouts based on chemical oxidation and reduction processes.

Journal

Asian Journal of Organic ChemistryWiley

Published: May 1, 2014

Keywords: ; ; ; ;

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