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A One‐Pot Strategy for the Synthesis of β‐Substituted Rhoda‐ and Irida‐Carbolong Complexes

A One‐Pot Strategy for the Synthesis of β‐Substituted Rhoda‐ and Irida‐Carbolong Complexes Starting from an organic multiyne, three steps are normally needed for the preparation of non‐β‐phosphonium functionalized rhoda‐ and irida‐carbolong complexes. Herein, a one‐pot strategy, by mixing a multiyne, a nucleophile, and RhCl(CO)(PPh3)2/AgBF4 or [Ir(CH3CN)(CO)(PPh3)2]BF4, was developed to achieve a series of β‐functionalized rhoda‐ and irida‐carbolong complexes. The β‐substituents in these complexes can be various C‐, N‐ and O‐centered groups, dependent on the nucleophiles used. This strategy provides a new convenient route to construct carbolong complexes, which is important for the further development of carbolong chemistry. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Chinese Journal of Chemistry Wiley

A One‐Pot Strategy for the Synthesis of β‐Substituted Rhoda‐ and Irida‐Carbolong Complexes

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References (72)

Publisher
Wiley
Copyright
© 2022 SIOC, CAS, Shanghai, & WILEY‐VCH GmbH
eISSN
1614-7065
DOI
10.1002/cjoc.202200179
Publisher site
See Article on Publisher Site

Abstract

Starting from an organic multiyne, three steps are normally needed for the preparation of non‐β‐phosphonium functionalized rhoda‐ and irida‐carbolong complexes. Herein, a one‐pot strategy, by mixing a multiyne, a nucleophile, and RhCl(CO)(PPh3)2/AgBF4 or [Ir(CH3CN)(CO)(PPh3)2]BF4, was developed to achieve a series of β‐functionalized rhoda‐ and irida‐carbolong complexes. The β‐substituents in these complexes can be various C‐, N‐ and O‐centered groups, dependent on the nucleophiles used. This strategy provides a new convenient route to construct carbolong complexes, which is important for the further development of carbolong chemistry.

Journal

Chinese Journal of ChemistryWiley

Published: Aug 1, 2022

Keywords: Carbolong chemistry; Metallacycles; Rhodium; Iridium; Tridentate ligands

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