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Tsutomu Mizuta, Jun Wang, K. Miyoshi (1995)
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A novel Co (II) ‐ Na (I) heterometallic coordination polymer {[CoNa (NTA) (H2O)3] · 2H2O}n (NTA = nitrilotriacetate) was synthesized and characterized by elemental analysis and X‐ray diffraction study. The electrochemical behavior in aqueous solution was measured by cyclic voltammetry, indicating a quasi‐reversible process. The complex crystallizes in the orthorhombic space group Pbca with the cell parameters a = 1.47276 (3) nm, b = 0.97280 (3) nm, c = 1.92946 (6) nm, V = 2.76434 (13) nm3, Z = 8. In the title complex, there are two kinds of zigzag chains which interconnect together to form 2D network. One stretches along the b‐axis, comprising Co (II) ions, the other stretches along the c‐axis, comprising Na (I) ions.
Chinese Journal of Chemistry – Wiley
Published: Mar 1, 2002
Keywords: ; ; ; ;
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