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A Nitrilotriacetate Bridged Heteronuclear Co (II)‐Na (I) Polymer: {[CoNa (NTA) (H2O)3] · 2H2O}n

A Nitrilotriacetate Bridged Heteronuclear Co (II)‐Na (I) Polymer: {[CoNa (NTA) (H2O)3] · 2H2O}n A novel Co (II) ‐ Na (I) heterometallic coordination polymer {[CoNa (NTA) (H2O)3] · 2H2O}n (NTA = nitrilotriacetate) was synthesized and characterized by elemental analysis and X‐ray diffraction study. The electrochemical behavior in aqueous solution was measured by cyclic voltammetry, indicating a quasi‐reversible process. The complex crystallizes in the orthorhombic space group Pbca with the cell parameters a = 1.47276 (3) nm, b = 0.97280 (3) nm, c = 1.92946 (6) nm, V = 2.76434 (13) nm3, Z = 8. In the title complex, there are two kinds of zigzag chains which interconnect together to form 2D network. One stretches along the b‐axis, comprising Co (II) ions, the other stretches along the c‐axis, comprising Na (I) ions. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Chinese Journal of Chemistry Wiley

A Nitrilotriacetate Bridged Heteronuclear Co (II)‐Na (I) Polymer: {[CoNa (NTA) (H2O)3] · 2H2O}n

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References (10)

Publisher
Wiley
Copyright
Copyright © 2002 Wiley Subscription Services, Inc., A Wiley Company
ISSN
1001-604X
eISSN
1614-7065
DOI
10.1002/cjoc.20020200306
Publisher site
See Article on Publisher Site

Abstract

A novel Co (II) ‐ Na (I) heterometallic coordination polymer {[CoNa (NTA) (H2O)3] · 2H2O}n (NTA = nitrilotriacetate) was synthesized and characterized by elemental analysis and X‐ray diffraction study. The electrochemical behavior in aqueous solution was measured by cyclic voltammetry, indicating a quasi‐reversible process. The complex crystallizes in the orthorhombic space group Pbca with the cell parameters a = 1.47276 (3) nm, b = 0.97280 (3) nm, c = 1.92946 (6) nm, V = 2.76434 (13) nm3, Z = 8. In the title complex, there are two kinds of zigzag chains which interconnect together to form 2D network. One stretches along the b‐axis, comprising Co (II) ions, the other stretches along the c‐axis, comprising Na (I) ions.

Journal

Chinese Journal of ChemistryWiley

Published: Mar 1, 2002

Keywords: ; ; ; ;

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