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- Publisher
- Wiley
- Copyright
- Copyright © 2010 Wiley Periodicals, Inc.
- ISSN
- 1042-7163
- eISSN
- 1098-1071
- DOI
- 10.1002/hc.20579
- Publisher site
- See Article on Publisher Site
Abstract
New platinum complexes of the type cis‐Pt(L)2Cl2 have been synthesized from five‐ and six‐membered cyclic phosphines, which were prepared after deoxygenating a series of phosphine oxides (3‐phospholene oxides, phospholane oxides, a 1,4‐dihydrophosphinine oxide, and a 1,2,3,6‐tetrahydrophosphinine oxide). The complexes were characterized by NMR and mass spectral data, and their stereostructures were elucidated by B3LYP/6‐31G(d)‐LANL2DZ ECP calculations. The phosphine intermediates were characterized as the corresponding phosphine‐boranes. © 2010 Wiley Periodicals, Inc. Heteroatom Chem 21:63–70, 2010; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20579
Journal
Heteroatom Chemistry – Wiley
Published: Jan 1, 2010