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- Publisher
- Wiley
- Copyright
- Copyright © 2016 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim
- ISSN
- 1614-6832
- eISSN
- 1614-6840
- DOI
- 10.1002/aenm.201600826
- Publisher site
- See Article on Publisher Site
Abstract
CommuniCtion www.advenergymat.de www.MaterialsViews.com A High Power Rechargeable Nonaqueous Multivalent Zn/V O Battery 2 5 Premkumar Senguttuvan, Sang-Don Han, Soojeong Kim, Albert L. Lipson, Sanja Tepavcevic, Timothy T. Fister, Ira D. Bloom, Anthony K. Burrell, and Christopher S. Johnson* [5,6] Expanding electrified transportation, and developing new large- host lattice, and recently proposed under-coordinated Mo size grid energy storage will require battery technologies that metal atoms at the surface that assist as a catalyst in desolvation 2+ [7] are scalable with high energy density, fast charge/discharge of the Mg in electrolyte solution. time, safety, low cost, and be eco-friendly. To advance battery In order to improve multivalent ion intercalation in oxides technologies and storage beyond Li-ion energy density will (intrinsically higher voltage materials with respect to sulfides), require new electrode materials and electrolyte chemistries that strategies including nanosizing and incorporation of water or 2+ 2+ 2+ can support multivalent cation intercalation (Mg , Zn , Ca , solvent molecules into host crystalline structures have been 3+ [8–10] Al ) at the cathode and reversible respective metal-only deposi- reported to be successful. The water/solvent mole cules [1] tion/stripping at the anode. While elevating the multivalent facilitate the reaction, perhaps by coordinating (stabilizing)
Journal
Advanced Energy Materials – Wiley
Published: Dec 1, 2016
Keywords: ; ; ; ;