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G. Kirby, M. Mahajan, M. Rahman (1991)
α-Alkylation of the Diels–Alder cycloadducts of the thioaldehyde, ethyl thioxoacetateJournal of The Chemical Society-perkin Transactions 1
G. Capozzi, S. Menichetti, C. Nativi, Alessandro Rosi, G. Valle (2010)
Phthalimidosulfenyl Chloride. Part 5. Reaction with Enolizable Carbonyl Compounds and Synthesis of Functionalized Thiones.ChemInform, 24
E. Vedejs, D. Perry, K. Houk, N. Rondan (1983)
Regiochemistry in thiocarbonyl Diels-Alder additions: reversal of selectivity by substituent effects in thioaldehydesJournal of the American Chemical Society, 105
H. Morita, M. Takeda, H. Kamiyama, Tadaaki Hashimoto, T. Yoshimura, C. Shimasaki, E. Tsukurimichi (1996)
Thiapyran formation via an unexpected thioaldehyde intermediate by the thermal decomposition of phenacyl sulfoxides bearing some heterocyclesTetrahedron Letters, 37
C. Bladon, Irene Ferguson, G. Kirby, A. Lochead, D. Mcdougall (1983)
Generation of ethyl thioxoacetate, a dienophilic thioaldehydeJournal of The Chemical Society, Chemical Communications
E. Vedejs, J. Stults, R. Wilde (1988)
Diastereoselectivity in the Diels-Alder reactions of thio aldehydesJournal of the American Chemical Society, 110
G. Kirby, A. Lochead, G. Sheldrake (1984)
Transformation of thiosulphonates into α-sulphonyldisulphides, a new class of thioaldehyde precursorsJournal of The Chemical Society, Chemical Communications
E. Vedejs, T. Eberlein, D. Mazur, C. Mcclure, D. Perry, R. Ruggeri, E. Schwartz, J. Stults, D. Varie (1986)
Thioaldehyde Diels-Alder reactionsJournal of Organic Chemistry, 51
E. Vedejs, J. Stults (1988)
Synthesis of azocine derivatives from thio aldehyde Diels-Alder adductsJournal of Organic Chemistry, 53
A. Wang, K. Brower, D. Naud (1997)
Effect of Pressure on the Thermolysis of Nitroalkanes in SolutionJournal of Organic Chemistry, 62
J. Baldwin, R. Lopez (1983)
The generation and trapping of thiobenzaldehyde and thioacetaldehydeJournal of The Chemical Society, Chemical Communications
E. Vedejs, T. Eberlein, R. Wilde (1988)
Internal thioaldehyde trapping by enes and dienesJournal of Organic Chemistry, 53
G. Kirby, A. Lochead, G. Sheldrake (1984)
Generation of thioaldehydes from sodium thiosulphate S-esters (Bunte salts)Journal of The Chemical Society, Chemical Communications
Previously, a facile formation of a thioaldehyde by the thermolysis of a heteroaryl phenacyl sulfoxide was confirmed by the detection of a cycloadduct with 2,3‐dimethyl‐1,3‐butadiene. The usefulness of benzothiazolyl phenacyl sulfoxide as a precursor for 2‐oxo‐2‐phenylethanethial was studied under the same conditions in the presence of various dienes and anthracene. In all cases, the Diels‐Alder cycloadducts were formed in moderate to good yields, and the addition of triethylamine as external base was revealed to be effective for carrying out the thermolysis under milder reaction conditions and for the improvement of yields. © 1999 John Wiley & Sons, Inc. Heteroatom Chem 10: 363–367, 1999
Heteroatom Chemistry – Wiley
Published: Jan 1, 1999
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