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1‐(2,4,6‐Trialkylphenyl)phospholes 1a,b possess a moderate aromatic character. Despite of that they underwent a sigmatropic rearrangement at 150°C to afford 2H‐phospholes 2a,b which by trapping with tolane, or in reaction with another unit of 2 gave (4 + 2) cycloadducts 3a,b, or in a reversible reaction, dimer 6, respectively. Dedimerization of species 6 at 150°C in the presence of tolane, or at 0°C under oxidative circumstances, led to 1‐phosphanorbornadiene 3a, or phosphole oxide dimer 8, respectively. © 2003 Wiley Periodicals, Inc. Heteroatom Chem 14:316–319, 2003; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.10151
Heteroatom Chemistry – Wiley
Published: Jan 1, 2003
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