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(1‐Me‐1‐ closo ‐SnB 11 H 11 ) − as a potential weakly coordinating anion: Synthesis of Rh(PPh 3 ) 2 (1‐Me‐ closo ‐SnB 11 H 11 ) and comparisons with Rh(PR 3 ) 2 (1‐H‐ closo ‐CB 11 H 11 )

(1‐Me‐1‐ closo ‐SnB 11 H 11 ) − as a potential weakly coordinating anion: Synthesis of Rh(PPh 3 )... The closo‐stannaborane salt (Rh(PPh3)2‐(nbd))(1‐Me‐1‐closo‐SnB11H11) reacts with H2 in CH2 Cl2 solution to afford the contact ion‐pair Rh(PPh3)2(1‐Me‐closo‐SnB11H11), which has been characterized in solution and the solid state by X‐ray diffraction. © 2006 Wiley Periodicals, Inc. Heteroatom Chem 17:174–180, 2006; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20218 http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Heteroatom Chemistry Wiley

(1‐Me‐1‐ closo ‐SnB 11 H 11 ) − as a potential weakly coordinating anion: Synthesis of Rh(PPh 3 ) 2 (1‐Me‐ closo ‐SnB 11 H 11 ) and comparisons with Rh(PR 3 ) 2 (1‐H‐ closo ‐CB 11 H 11 )

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References (24)

Publisher
Wiley
Copyright
Copyright © 2006 Wiley Periodicals, Inc.
ISSN
1042-7163
eISSN
1098-1071
DOI
10.1002/hc.20218
Publisher site
See Article on Publisher Site

Abstract

The closo‐stannaborane salt (Rh(PPh3)2‐(nbd))(1‐Me‐1‐closo‐SnB11H11) reacts with H2 in CH2 Cl2 solution to afford the contact ion‐pair Rh(PPh3)2(1‐Me‐closo‐SnB11H11), which has been characterized in solution and the solid state by X‐ray diffraction. © 2006 Wiley Periodicals, Inc. Heteroatom Chem 17:174–180, 2006; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20218

Journal

Heteroatom ChemistryWiley

Published: Jan 1, 2006

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