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1‐(alkylthio)‐polyfluoroalkynes. Reactions with mercaptans and thermal transformations

1‐(alkylthio)‐polyfluoroalkynes. Reactions with mercaptans and thermal transformations 1‐(Alkylthio)difluoropropynes regioselectively add dialkylamines and mercaptans with formation of 1‐(alkylthio)‐2‐dialkylamino(alkylthio)ethenes, which exist only in the form of one (presumably the trans isomer) geometrical isomer. Thermal transformation of 1‐(alkylthio)difluoropropynes occurs at a temperature of under 100°C and leads to the formation of 2,4‐bis(polyfluoroalkyl)‐3‐(alkylthio)thiophenes. © 1998 John Wiley & Sons, Inc.Heteroatom Chem 9:151–154, 1998 http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Heteroatom Chemistry Wiley

1‐(alkylthio)‐polyfluoroalkynes. Reactions with mercaptans and thermal transformations

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References (4)

Publisher
Wiley
Copyright
Copyright © 1998 Wiley Subscription Services
ISSN
1042-7163
eISSN
1098-1071
DOI
10.1002/(SICI)1098-1071(1998)9:2<151::AID-HC9>3.0.CO;2-F
Publisher site
See Article on Publisher Site

Abstract

1‐(Alkylthio)difluoropropynes regioselectively add dialkylamines and mercaptans with formation of 1‐(alkylthio)‐2‐dialkylamino(alkylthio)ethenes, which exist only in the form of one (presumably the trans isomer) geometrical isomer. Thermal transformation of 1‐(alkylthio)difluoropropynes occurs at a temperature of under 100°C and leads to the formation of 2,4‐bis(polyfluoroalkyl)‐3‐(alkylthio)thiophenes. © 1998 John Wiley & Sons, Inc.Heteroatom Chem 9:151–154, 1998

Journal

Heteroatom ChemistryWiley

Published: Jan 1, 1998

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