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E. Peled (1979)
The Electrochemical Behavior of Alkali and Alkaline Earth Metals in Nonaqueous Battery Systems—The Solid Electrolyte Interphase ModelJournal of The Electrochemical Society, 126
B. Ravel, M. Newville (2005)
ATHENA and ARTEMIS: interactive graphical data analysis using IFEFFITPhysica Scripta, 2005
P. Verma, P. Maire, P. Novák (2010)
A review of the features and analyses of the solid electrolyte interphase in Li-ion batteriesElectrochimica Acta, 55
G Brown, B Gu (2006)
Perchlorate
S. Shi, Peng Lu, Zhongyi Liu, Y. Qi, L. Hector, Hong Li, S. Harris (2012)
Direct calculation of Li-ion transport in the solid electrolyte interphase.Journal of the American Chemical Society, 134 37
A. Shchukarev, D. Korolkov (2004)
XPS Study of group IA carbonatesCentral European Journal of Chemistry, 2
R. Quinlan, Yi‐Chun Lu, Y. Shao-horn, A. Mansour (2013)
XPS Studies of Surface Chemistry Changes of LiNi0.5Mn0.5O2 Electrodes during High-Voltage CyclingJournal of The Electrochemical Society, 160
K. Xu (2004)
Nonaqueous liquid electrolytes for lithium-based rechargeable batteries.Chemical reviews, 104 10
Peng Lu, Chen Li, E. Schneider, S. Harris (2014)
Chemistry, Impedance, and Morphology Evolution in Solid Electrolyte Interphase Films during Formation in Lithium Ion BatteriesJournal of Physical Chemistry C, 118
G. Cherkashinin, K. Nikolowski, H. Ehrenberg, S. Jacke, L. Dimesso, W. Jaegermann (2012)
The stability of the SEI layer, surface composition and the oxidation state of transition metals at the electrolyte-cathode interface impacted by the electrochemical cycling: X-ray photoelectron spectroscopy investigation.Physical chemistry chemical physics : PCCP, 14 35
M. Seah, W. Dench (1979)
Quantitative electron spectroscopy of surfaces: A standard data base for electron inelastic mean free paths in solidsSurface and Interface Analysis, 1
Yifeng Wang, X. Guo, S. Greenbaum, Jun Liu, K. Amine (2001)
Solid Electrolyte Interphase Formation on Lithium-Ion Electrodes: A 7Li Nuclear Magnetic Resonance StudyElectrochemical and Solid State Letters, 4
Hong-Li Zhang, Feng Li, Chang Liu, Junyang Tan, Hui‐Ming Cheng (2005)
New insight into the solid electrolyte interphase with use of a focused ion beam.The journal of physical chemistry. B, 109 47
Fu-Ming Wang, Meng-Han Yu, Yi-Ju Hsiao, Ying Tsai, B. Hwang, Yung‐Yun Wang, C. Wan (2011)
Aging Effects to Solid Electrolyte Interface (SEI) Membrane Formation and the Performance Analysis of Lithium Ion BatteriesInternational Journal of Electrochemical Science
Yi‐Chun Lu, A. Mansour, N. Yabuuchi, Y. Shao-horn (2009)
Probing the Origin of Enhanced Stability of AlPO4 Nanoparticle Coated LiCoO2 during Cycling to High Voltages: Combined XRD and XPS StudiesChemistry of Materials, 21
(2004)
Synchrotron Xray studies of the solid electrolyte interface on cycled lithium-ion battery cathodes. In: Power sources for transportation
F. Ding, Wu Xu, G. Graff, Jian Zhang, M. Sushko, Xilin Chen, Yuyan Shao, M. Engelhard, Z. Nie, Jie Xiao, Xingjiang Liu, P. Sushko, Jun Liu, Ji‐Guang Zhang (2013)
Dendrite-free lithium deposition via self-healing electrostatic shield mechanism.Journal of the American Chemical Society, 135 11
C. Powell, A. Jablonski (1999)
Evaluation of Calculated and Measured Electron Inelastic Mean Free Paths Near Solid SurfacesJournal of Physical and Chemical Reference Data, 28
Peng Lu, S. Harris (2011)
Lithium transport within the solid electrolyte interphaseElectrochemistry Communications, 13
U. Troeltzsch, O. Kanoun, H. Tränkler (2006)
Characterizing aging effects of lithium ion batteries by impedance spectroscopyElectrochimica Acta, 51
D. Martin‐Vosshage, B. Chowdari (1995)
XPS studies on (PEO){sub n}LiClO{sub 4} and (PEO){sub n} Cu(ClO{sub 4}){sub 2} polymer electrolytesJournal of The Electrochemical Society, 142
D. Aurbach, K. Gamolsky, B. Markovsky, G. Salitra, Y. Gofer, U. Heider, R. Oesten, Michael Schmidt (2000)
The Study of Surface Phenomena Related to Electrochemical Lithium Intercalation into Li x MO y Host Materials (M = Ni, Mn)Journal of The Electrochemical Society, 147
K. Edström, T. Gustafsson, J. Thomas (2004)
The cathode-electrolyte interface in the Li-ion batteryElectrochimica Acta, 50
F. Blanc, M. Leskes, C. Grey (2013)
In situ solid-state NMR spectroscopy of electrochemical cells: batteries, supercapacitors, and fuel cells.Accounts of chemical research, 46 9
C. Patridge, C. Love, K. Swider-Lyons, M. Twigg, D. Ramaker (2013)
In-Situ X-ray Absorption Spectroscopy Analysis of Capacity Fade in Nanoscale-LiCoO2Journal of Solid State Chemistry, 203
M. Itagaki, Nao Kobari, Sachiko Yotsuda, Kunihiro Watanabe, S. Kinoshita, M. Ue (2005)
LiCoO2 electrode/electrolyte interface of Li-ion rechargeable batteries investigated by in situ electrochemical impedance spectroscopyJournal of Power Sources, 148
Matthew Pinson, M. Bazant (2012)
Theory of SEI Formation in Rechargeable Batteries: Capacity Fade, Accelerated Aging and Lifetime PredictionJournal of The Electrochemical Society, 160
L. Daheron, H. Martínez, R. Dedryvère, I. Baraille, M. Ménétrier, C. Denage, C. Delmas, D. Gonbeau (2009)
Surface Properties of LiCoO2 Investigated by XPS Analyses and Theoretical CalculationsJournal of Physical Chemistry C, 113
G. Brown, B. Gu (2006)
The Chemistry of Perchlorate in the Environment
R. Paynter, M. Edgell, J. Castle (1986)
The use of monochromatic Ag Lα radiation to study relaxation energy differences in X-ray photoelectron spectroscopy of alkali metal chloridesJournal of Electron Spectroscopy and Related Phenomena, 40
M. Herstedt, Mårten Stjerndahl, Anton Nytén, T. Gustafsson, H. Rensmo, H. Siegbahn, N. Ravet, M. Armand, J. Thomas, K. Edström (2003)
Surface chemistry of carbon-treated LiFePO4 particles for Li-ion battery cathodes studied by PESElectrochemical and Solid State Letters, 6
K Leung (2013)
Electronic structure modeling of electrochemical reactions at electrode/electrolyte interfaces in lithium ion batteriesJ Phys Chem C, 117
L. Daheron, R. Dedryvère, H. Martínez, M. Ménétrier, C. Denage, C. Delmas, D. Gonbeau (2008)
Electron Transfer Mechanisms upon Lithium Deintercalation from LiCoO2 to CoO2 Investigated by XPSChemistry of Materials, 20
C. Love, A. Korovina, C. Patridge, K. Swider-Lyons, M. Twigg, D. Ramaker (2013)
Review of LiFePO4 Phase Transition Mechanisms and New Observations from X-ray Absorption SpectroscopyJournal of The Electrochemical Society, 160
D. Ensling, A. Thissen, W. Jaegermann (2008)
On the formation of lithium oxides and carbonates on Li metal electrodes in comparison to LiCoO2 surface phases investigated by photoelectron spectroscopyApplied Surface Science, 255
Y. Tardy, L. Gartner (1977)
Relationships among Gibbs energies of formation of sulfates, nitrates, carbonates, oxides and aqueous ionsContributions to Mineralogy and Petrology, 63
J. Scofield (1973)
Theoretical photoionization cross sections from 1 to 1500 keV.
S. Takeuchi, T. Fukutsuka, K. Miyazaki, T. Abe (2013)
Electrochemical lithium ion intercalation into graphite electrode in propylene carbonate-based electrolytes with dimethyl carbonate and calcium saltJournal of Power Sources, 238
Sang-Pil Kim, A. Duin, V. Shenoy (2011)
Effect of electrolytes on the structure and evolution of the solid electrolyte interphase (SEI) in Li-ion batteries: A molecular dynamics studyJournal of Power Sources, 196
C. Grey, N. Dupré (2004)
NMR studies of cathode materials for lithium-ion rechargeable batteries.Chemical reviews, 104 10
M. Balasubramanian, Hungsui Lee, X. Sun, Xiao‐Qing Yang, A. Moodenbaugh, J. Mcbreen, D. Fischer, Zugen Fu (2002)
FORMATION OF SEI ON CYCLED LITHIUM-ION BATTERY CATHODES: SOFT X-RAY ABSORPTION STUDYElectrochemical and Solid State Letters, 5
Sara Malmgren, Katarzyna Ciosek, M. Hahlin, T. Gustafsson, M. Gorgoi, H. Rensmo, K. Edström (2013)
Comparing anode and cathode electrode/electrolyte interface composition and morphology using soft and hard X-ray photoelectron spectroscopyElectrochimica Acta, 97
S. Verdier, L. Ouatani, R. Dedryvère, F. Bonhomme, P. Biensan, D. Gonbeau (2007)
XPS Study on Al2O3- and AlPO4-Coated LiCoO2 Cathode Material for High-Capacity Li Ion BatteriesJournal of The Electrochemical Society, 154
J. Lei, Lingjie Li, R. Kostecki, R. Muller, F. Mclarnon (2004)
Characterization of SEI Layers on LiMn2O4 Cathodes with In Situ Spectroscopic EllipsometryJournal of The Electrochemical Society, 152
K. Leung (2012)
Electronic Structure Modeling of Electrochemical Reactions at Electrode/Electrolyte Interfaces in Lithium Ion BatteriesThe Journal of Physical Chemistry, 117
D. Aurbach, M. Daroux, Peter Faguy, E. Yeager (1987)
Identification of Surface Films Formed on Lithium in Propylene Carbonate SolutionsJournal of The Electrochemical Society, 134
Chenghuan Huang, Shu-xin Zhuang, Fei‐yue Tu (2013)
Electrode/Electrolyte Interfacial Behaviors of LiCoO2/Mixed Graphite Li-Ion Cells during Operation and StorageJournal of The Electrochemical Society, 160
F. Nobili, Sonia Dsoke, F. Croce, R. Marassi (2005)
An ac impedance spectroscopic study of Mg-doped LiCoO2 at different temperatures: electronic and ionic transport propertiesElectrochimica Acta, 50
Zhaoxiang Wang, Xuejie Huang, Liquan Chen (2004)
Characterization of Spontaneous Reactions of LiCoO2 with Electrolyte Solvent for Lithium-Ion BatteriesJournal of The Electrochemical Society, 151
W. Morgan, J. Wazer, W. Stec (1973)
Inner-orbital photoelectron spectroscopy of the alkali metal halides, perchlorates, phosphates, and pyrophosphatesJournal of the American Chemical Society, 95
T. Eriksson, A. Andersson, Andrea Bishop, C. Gejke, T. Gustafsson, J. Thomas (2002)
Surface analysis of LiMn2O4 electrodes in carbonate based electrolytesJournal of The Electrochemical Society, 149
D Martin-Vosshage, BVR Chowdari (1995)
XPS studies on (PEO)n LiClO4 and (PEO)n Cu(ClO4) 2 polymer electrolytesJ Electrochem Soc, 142
Shengbo Zhang (2006)
A review on electrolyte additives for lithium-ion batteriesJournal of Power Sources, 162
D. Aurbach, B. Markovsky, A. Rodkin, E. Levi, Y. Cohen, Hyeong-Jin Kim, Michael Schmidt (2002)
On the capacity fading of LiCoO2 intercalation electrodes:: the effect of cycling, storage, temperature, and surface film forming additivesElectrochimica Acta, 47
X. Qiu, Q. Zhuang, Qian-Qian Zhang, Ru Cao, Peng-Zhan Ying, Ying-Huai Qiang, Shi-Gang Sun (2012)
Electrochemical and electronic properties of LiCoO2 cathode investigated by galvanostatic cycling and EIS.Physical chemistry chemical physics : PCCP, 14 8
We introduce low levels of CsClO4 and RbClO4 into the electrolyte of LiCoO2 electrochemical half-cells to probe the composition of the passivation film on the surface of the cathode, the electrolyte decomposition layer (EDL). The advantages of these heavy alkali dopants lie in their large ionic radii, which limit intercalation, yet their strong light scattering cross-section creates a beacon that highlights the formation of products near the cathode surface. Detailed surface analysis and depth profiling with X-ray photoelectron spectroscopy, and bulk analysis utilizing X-ray absorption spectroscopy, show evidence for the formation of Cs/Rb compounds, such as carbonates, halides, and perchlorates, similar to those formed by lithium in previous studies, but also reveal the significantly reduced mobility of the Cs/Rb relative to Li in the non-uniform EDL. This unique approach could open several presently untapped techniques to gather new information on the EDL in Li-ion batteries.
Ionics – Springer Journals
Published: Aug 21, 2015
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