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Universal method for the functionalization of β-bromovinyl trifluoromethyl ketones of cyclobutene series

Universal method for the functionalization of β-bromovinyl trifluoromethyl ketones of cyclobutene... ISSN 00125008, Doklady Chemistry, 2010, Vol. 432, Part 1, pp. 133–135. © Pleiades Publishing, Ltd., 2010. Original Russian Text © A.B. Koldobskii, N.P. Tsvetkov, V.N. Kalinin, 2010, published in Doklady Akademii Nauk, 2010, Vol. 432, No. 2, pp. 188–190. CHEMISTRY Universal Method for the Functionalization of βBromovinyl Trifluoromethyl Ketones of Cyclobutene Series A. B. Koldobskii, N. P. Tsvetkov, and V. N. Kalinin Presented by Academician Yu.N. Bubnov October 14, 2009 Received November 10, 2009 DOI: 10.1134/S0012500810050046 Unsaturated trifluoromethyl ketones are a new tuted fluorinecontaining enones [5], whereas similar enones with the C=C bond being incorporated into a extremely promising class of compounds whose prop erties in recent two decades have been intensively strained small ring have been unknown until recently. studied in medicine [1], biochemistry [2], and molec Very recently, we found an unusual reaction of ular biology [3]. Moreover, these compounds are [2+2] cycloaddition of 1trifluoroacetyl2haloacety widely used in organic synthesis [4]. It is of special lenes to simple alkenes that proceeded in the absence synthetic interest to use unsaturated trifluoromethyl of light and catalyst to give βhalovinyl trifluoromethyl ketones containing a leaving group in the β position, ketones of cyclobutene series [6, 7]. With the use of http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Doklady Chemistry Springer Journals

Universal method for the functionalization of β-bromovinyl trifluoromethyl ketones of cyclobutene series

Koldobskii, A.; Tsvetkov, N.; Kalinin, V.
Doklady Chemistry , Volume 432 (1) – May 20, 2010
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References (7)

Publisher
Springer Journals
Copyright
Copyright © 2010 by Pleiades Publishing, Ltd.
Subject
Chemistry; Industrial Chemistry/Chemical Engineering; Chemistry/Food Science, general
ISSN
0012-5008
eISSN
1608-3113
DOI
10.1134/S0012500810050046
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See Article on Publisher Site

Abstract

ISSN 00125008, Doklady Chemistry, 2010, Vol. 432, Part 1, pp. 133–135. © Pleiades Publishing, Ltd., 2010. Original Russian Text © A.B. Koldobskii, N.P. Tsvetkov, V.N. Kalinin, 2010, published in Doklady Akademii Nauk, 2010, Vol. 432, No. 2, pp. 188–190. CHEMISTRY Universal Method for the Functionalization of βBromovinyl Trifluoromethyl Ketones of Cyclobutene Series A. B. Koldobskii, N. P. Tsvetkov, and V. N. Kalinin Presented by Academician Yu.N. Bubnov October 14, 2009 Received November 10, 2009 DOI: 10.1134/S0012500810050046 Unsaturated trifluoromethyl ketones are a new tuted fluorinecontaining enones [5], whereas similar enones with the C=C bond being incorporated into a extremely promising class of compounds whose prop erties in recent two decades have been intensively strained small ring have been unknown until recently. studied in medicine [1], biochemistry [2], and molec Very recently, we found an unusual reaction of ular biology [3]. Moreover, these compounds are [2+2] cycloaddition of 1trifluoroacetyl2haloacety widely used in organic synthesis [4]. It is of special lenes to simple alkenes that proceeded in the absence synthetic interest to use unsaturated trifluoromethyl of light and catalyst to give βhalovinyl trifluoromethyl ketones containing a leaving group in the β position, ketones of cyclobutene series [6, 7]. With the use of

Journal

Doklady Chemistry – Springer Journals

Published: May 20, 2010

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