Access the full text.
Sign up today, get DeepDyve free for 14 days.
M. Avdeev, C. Ling, T. Tan, Sean Li, Gosuke Oyama, A. Yamada, P. Barpanda (2014)
Magnetic structure and properties of the rechargeable battery insertion compound Na2FePO4F.Inorganic chemistry, 53 2
Weixin Song, Xiaobo Ji, Zheng-ping Wu, Yirong Zhu, Yao Yinpeng, Huangfu Kaili, Qi-yuan Chen, C. Banks (2014)
Na2FePO4F cathode utilized in hybrid-ion batteries: a mechanistic exploration of ion migration and diffusion capabilityJournal of Materials Chemistry, 2
Y. Kawabe, N. Yabuuchi, Masataka Kajiyama, N. Fukuhara, Tokuo Inamasu, R. Okuyama, I. Nakai, S. Komaba (2011)
Synthesis and electrode performance of carbon coated Na2FePO4F for rechargeable Na batteriesElectrochemistry Communications, 13
Nadir Recham, J. Chotard, L. Dupont, K. Djellab, M. Armand, J. Tarascon (2009)
Ionothermal Synthesis of Sodium-Based Fluorophosphate Cathode MaterialsJournal of The Electrochemical Society, 156
Markas Law, V. Ramar, P. Balaya (2015)
Synthesis, characterisation and enhanced electrochemical performance of nanostructured Na2FePO4F for sodium batteriesRSC Advances, 5
P. Barpanda, Yasunobu Yamashita, Yuki Yamada, A. Yamada (2013)
High-Throughput Solution Combustion Synthesis of High-Capacity LiFeBO3 CathodeJournal of The Electrochemical Society, 160
K. Momma, F. Izumi (2011)
VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology dataJournal of Applied Crystallography, 44
H. Rietveld (1969)
A profile refinement method for nuclear and magnetic structuresJournal of Applied Crystallography, 2
(1994)
General Structure Analysis System (GSAS); Los Alamos National Laboratory Report, LAUR 86-748
P. Barpanda, Tiannan Ye, Sai-Cheong Chung, Yuki Yamada, S. Nishimura, A. Yamada (2012)
Eco-efficient splash combustion synthesis of nanoscale pyrophosphate (Li2FeP2O7) positive-electrode using Fe(III) precursorsJournal of Materials Chemistry, 22
B. Dunn, H. Kamath, J. Tarascon (2011)
Electrical Energy Storage for the Grid: A Battery of ChoicesScience, 334
B. Ellis, W. Makahnouk, W. Rowan-Weetaluktuk, D. Ryan, L. Nazar (2010)
Crystal Structure and Electrochemical Properties of A2MPO4F Fluorophosphates (A = Na, Li; M = Fe, Mn, Co, Ni)†Chemistry of Materials, 22
N. Yabuuchi, K. Kubota, M. Dahbi, S. Komaba (2014)
Research development on sodium-ion batteries.Chemical reviews, 114 23
B. Toby (2001)
EXPGUI, a graphical user interface for GSASJournal of Applied Crystallography, 34
Dongming Cui, Shasha Chen, Han-Ching Chang, A. Chang-chun, Liangjie Yuan (2016)
Carbothermal reduction synthesis of carbon coated Na 2 FePO 4 F for lithium ion batteriesJournal of Power Sources, 301
L. Sharma, P. Nayak, E. Llave, Haomin Chen, S. Adams, D. Aurbach, P. Barpanda (2017)
Electrochemical and Diffusional Investigation of Na2FeIIPO4F Fluorophosphate Sodium Insertion Material Obtained from FeIII Precursor.ACS applied materials & interfaces, 9 40
N. Yabuuchi, S. Komaba (2014)
Recent research progress on iron- and manganese-based positive electrode materials for rechargeable sodium batteriesScience and Technology of Advanced Materials, 15
B. Ellis, W. Makahnouk, Y. Makimura, Kathryn Toghill, L. Nazar (2007)
A multifunctional 3.5 V iron-based phosphate cathode for rechargeable batteries.Nature materials, 6 10
Michael Slater, Donghan Kim, Eungje Lee, C. Johnson (2013)
Sodium‐Ion BatteriesAdvanced Functional Materials, 23
G. Kobayashi, S. Nishimura, Min‐Sik Park, R. Kanno, M. Yashima, T. Ida, A. Yamada (2009)
Isolation of Solid Solution Phases in Size‐Controlled LixFePO4 at Room TemperatureAdvanced Functional Materials, 19
Exploring soft-chemistry synthesis of Fe-based battery cathode materials, we have optimized combustion synthesis as an ultra-rapid approach to produce Na2FePO4F fluorophosphate cathode. It yields nanoscale, carbon-coated target product by annealing (at 600 °C) for just 1 min. The purity of the material crystallizing in the orthorhombic structure was confirmed by powder X-ray diffraction pattern and XPS analysis, while the morphology was studied by scanning electron microscopy. The as-synthesized material exhibits good electrochemical performance delivering a first discharge capacity of more than 70 mAh/g at C/10 rate versus both Li+/Li and Na+/Na, hence acting as an efficient host for both Li-ion and Na-ion insertion. Combustion synthesis can be employed as an economic route for synthesis and rapid screening of various phosphate-based insertion materials.
Ionics – Springer Journals
Published: Dec 7, 2017
Read and print from thousands of top scholarly journals.
Already have an account? Log in
Bookmark this article. You can see your Bookmarks on your DeepDyve Library.
To save an article, log in first, or sign up for a DeepDyve account if you don’t already have one.
Copy and paste the desired citation format or use the link below to download a file formatted for EndNote
Access the full text.
Sign up today, get DeepDyve free for 14 days.
All DeepDyve websites use cookies to improve your online experience. They were placed on your computer when you launched this website. You can change your cookie settings through your browser.