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Y. Tret'yakov (1978)
Tverdofaznye reaktsii
Doklady Chemistry, Vol. 392, Nos. 4–6, 2003, pp. 246–250. Translated from Doklady Akademii Nauk, Vol. 392, No. 6, 2003, pp. 771–775. Original Russian Text Copyright © 2003 by Antipov, Grigor’ev, Kolen’ko, Kaul’. CHEMISTRY Tunneling Magnetoresistance of La Sr MnO Ceramics 0.7 0.3 3 Obtained by Complexonate Homogenization A. B. Antipov, A. N. Grigor’ev, Yu. V. Kolen’ko, and A. R. Kaul’ Presented by Academician Yu.D. Tret’yakov July 5, 2003 Received July 7, 2003 The discovery of colossal magnetoresistance Another method of synthesis of oxide ceramic mate- (CMR) in doped manganites R A MnO (R = La, Pr, rials, referred to as complexonate homogenization [7, 1 Ð x x 3 Nd; A = Ca, Sr, Ba, Pb) with a perovskite structure has 8], is based on the formation of polynuclear heterome- drawn the attention of researchers to these complex oxides tallic complexonates, i.e., coordination compounds in as a new class of magnetosensitive materials [1–4]. The which different metal cations are bound together by large negative magnetoresistance observed in complex polydentate ligands. The initial reagents in this method manganites near the Curie temperature is due to sup- are solutions of different metals with complexones (eth- pression of spin fluctuations by a magnetic
Doklady Chemistry – Springer Journals
Published: Oct 5, 2004
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