Get 20M+ Full-Text Papers For Less Than $1.50/day. Start a 14-Day Trial for You or Your Team.

Learn More →

Topochemical aspects of the complexation of neodymium chloride with isopropyl alcohol in the synthesis of a catalyst for stereospecific isoprene polymerization

Topochemical aspects of the complexation of neodymium chloride with isopropyl alcohol in the... ISSN 00125008, Doklady Chemistry, 2011, Vol. 440, Part 2, pp. 286–288. © Pleiades Publishing, Ltd., 2011. Original Russian Text © Yu.V. Morozov, V.Z. Mingaleev, I.Sh. Nasyrov, V.P. Zakharov, Yu.B. Monakov, 2011, published in Doklady Akademii Nauk, 2011, Vol. 440, No. 5, pp. 643–645. CHEMISTRY Topochemical Aspects of the Complexation of Neodymium Chloride with Isopropyl Alcohol in the Synthesis of a Catalyst for Stereospecific Isoprene Polymerization Yu. V. Morozov, V. Z. Mingaleev, I. Sh. Nasyrov, V. P. Zakharov, and Academician Yu. B. Monakov Received May 4, 2011 DOI: 10.1134/S0012500811100077 Catalytic systems based on lanthanide compounds mostly determined by the particle sizes of the initial are efficient catalysts for diene polymerization. A spe reactants. cific feature of these systems is high cisstereospecific In the industrial isoprene rubber production in ity, in particular, the polybutadiene and polyisoprene Russia, alcohol complexes of neodymium chloride are synthesized in the presence of these systems contain currently used [5]. Therefore, in this work, we consid ~98% cis1,4units. ered an unconventional way of enhancing the com plexation of neodymium chloride with isopropyl alco Catalytic systems produced by the interaction of a hol in a single circulation of the reaction mixture lanthanide chloride (catalyst) and an organoalumi through http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Doklady Chemistry Springer Journals

Topochemical aspects of the complexation of neodymium chloride with isopropyl alcohol in the synthesis of a catalyst for stereospecific isoprene polymerization

Download PDF
3 pages

Loading next page...
 
/lp/springer-journals/topochemical-aspects-of-the-complexation-of-neodymium-chloride-with-l4JTd1a0TJ

References (2)

Publisher
Springer Journals
Copyright
Copyright © 2011 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
0012-5008
eISSN
1608-3113
DOI
10.1134/S0012500811100077
Publisher site
See Article on Publisher Site

Abstract

ISSN 00125008, Doklady Chemistry, 2011, Vol. 440, Part 2, pp. 286–288. © Pleiades Publishing, Ltd., 2011. Original Russian Text © Yu.V. Morozov, V.Z. Mingaleev, I.Sh. Nasyrov, V.P. Zakharov, Yu.B. Monakov, 2011, published in Doklady Akademii Nauk, 2011, Vol. 440, No. 5, pp. 643–645. CHEMISTRY Topochemical Aspects of the Complexation of Neodymium Chloride with Isopropyl Alcohol in the Synthesis of a Catalyst for Stereospecific Isoprene Polymerization Yu. V. Morozov, V. Z. Mingaleev, I. Sh. Nasyrov, V. P. Zakharov, and Academician Yu. B. Monakov Received May 4, 2011 DOI: 10.1134/S0012500811100077 Catalytic systems based on lanthanide compounds mostly determined by the particle sizes of the initial are efficient catalysts for diene polymerization. A spe reactants. cific feature of these systems is high cisstereospecific In the industrial isoprene rubber production in ity, in particular, the polybutadiene and polyisoprene Russia, alcohol complexes of neodymium chloride are synthesized in the presence of these systems contain currently used [5]. Therefore, in this work, we consid ~98% cis1,4units. ered an unconventional way of enhancing the com plexation of neodymium chloride with isopropyl alco Catalytic systems produced by the interaction of a hol in a single circulation of the reaction mixture lanthanide chloride (catalyst) and an organoalumi through

Journal

Doklady Chemistry – Springer Journals

Published: Nov 19, 2011

There are no references for this article.