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Thermodynamic properties of arsenic sulfides studied by EMF measurements

Thermodynamic properties of arsenic sulfides studied by EMF measurements The solid-state phase equilibria and thermodynamic properties of alloys in the As-S system have been studied using emf measurements. The temperature and composition dependences of the emf confirm the existence of As2S5, As2S3, AsS, and As4S3 with narrow homogeneity ranges. The emf data are used to calculate relative partial molar functions of the As in the alloys and the standard Gibbs energies and standard entropies of the arsenic sulfides. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Inorganic Materials Springer Journals

Thermodynamic properties of arsenic sulfides studied by EMF measurements

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References (19)

Publisher
Springer Journals
Copyright
Copyright © 2011 by Pleiades Publishing, Ltd.
Subject
Chemistry; Materials Science, general; Inorganic Chemistry ; Industrial Chemistry/Chemical Engineering
ISSN
0020-1685
eISSN
1608-3172
DOI
10.1134/S0020168511030034
Publisher site
See Article on Publisher Site

Abstract

The solid-state phase equilibria and thermodynamic properties of alloys in the As-S system have been studied using emf measurements. The temperature and composition dependences of the emf confirm the existence of As2S5, As2S3, AsS, and As4S3 with narrow homogeneity ranges. The emf data are used to calculate relative partial molar functions of the As in the alloys and the standard Gibbs energies and standard entropies of the arsenic sulfides.

Journal

Inorganic MaterialsSpringer Journals

Published: Mar 9, 2011

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