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The thermal properties of C60 and C70 fullerenes and fullerites have been studied by X-ray structural analysis and UV spectroscopy. It was shown that C70 fullerite is stabler than C60 fullerite (by ~150°C) due to the different geometry of the fullerenes and stronger intermolecular interactions. The experimental results are given a qualitative and quantitative interpretation based on the calculation of the interaction energy between two fullerene molecules.
High Temperature – Springer Journals
Published: Mar 1, 2021
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