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The unusual reaction of phenyltrifluorosilane with 2-aminoethanol and its N-methyl derivatives

The unusual reaction of phenyltrifluorosilane with 2-aminoethanol and its N-methyl derivatives ISSN 0012-5008, Doklady Chemistry, 2006, Vol. 409, Part 2, pp. 139–141. © Pleiades Publishing, Inc., 2006. Original Russian Text © M.G. Voronkov, E.A. Grebneva, O.M. Trofimova, N.F. Chernov, A.I. Albanov, N.N. Chipanina, 2006, published in Doklady Akademii Nauk, 2006, Vol. 409, No. 6, pp. 779–781. CHEMISTRY The Unusual Reaction of Phenyltrifluorosilane with 2-Aminoethanol and Its N-Methyl Derivatives Academician M. G. Voronkov, E. A. Grebneva, O. M. Trofimova, N. F. Chernov, A. I. Albanov, and N. N. Chipanina Received March 22, 2006 DOI: 10.1134/S0012500806080040 In the course of study of the C–Si bond cleavage in N N SiF phenyltrifluorosilane (PTS) with the aim of using PTS in the synthesis of organoelement compounds [1–6], (1) YH + C H SiF Y + C H 6 5 3 6 6 we studied the reaction of PTS with 2-aminoethanol Y = O, S and its N-methyl- and N,N-dimethyl derivatives. Previ- We also showed that the reaction of PTS with 2-amino- ously, we found that the reaction of protodesilylation of ethanol and its N-methyl and N,N-dimethyl derivatives PTS with 8-hydroxyquinoline or 8-mercaptoquinoline also involves the cleavage of the Ph–Si bond to give ben- leads to new intracomplex heterocyclic compounds, zene and (N Si) trifluoro(2-aminoethoxy)silane http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Doklady Chemistry Springer Journals

The unusual reaction of phenyltrifluorosilane with 2-aminoethanol and its N-methyl derivatives

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References (3)

Publisher
Springer Journals
Copyright
Copyright © 2006 by Pleiades Publishing, Inc.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
0012-5008
eISSN
1608-3113
DOI
10.1134/S0012500806080040
Publisher site
See Article on Publisher Site

Abstract

ISSN 0012-5008, Doklady Chemistry, 2006, Vol. 409, Part 2, pp. 139–141. © Pleiades Publishing, Inc., 2006. Original Russian Text © M.G. Voronkov, E.A. Grebneva, O.M. Trofimova, N.F. Chernov, A.I. Albanov, N.N. Chipanina, 2006, published in Doklady Akademii Nauk, 2006, Vol. 409, No. 6, pp. 779–781. CHEMISTRY The Unusual Reaction of Phenyltrifluorosilane with 2-Aminoethanol and Its N-Methyl Derivatives Academician M. G. Voronkov, E. A. Grebneva, O. M. Trofimova, N. F. Chernov, A. I. Albanov, and N. N. Chipanina Received March 22, 2006 DOI: 10.1134/S0012500806080040 In the course of study of the C–Si bond cleavage in N N SiF phenyltrifluorosilane (PTS) with the aim of using PTS in the synthesis of organoelement compounds [1–6], (1) YH + C H SiF Y + C H 6 5 3 6 6 we studied the reaction of PTS with 2-aminoethanol Y = O, S and its N-methyl- and N,N-dimethyl derivatives. Previ- We also showed that the reaction of PTS with 2-amino- ously, we found that the reaction of protodesilylation of ethanol and its N-methyl and N,N-dimethyl derivatives PTS with 8-hydroxyquinoline or 8-mercaptoquinoline also involves the cleavage of the Ph–Si bond to give ben- leads to new intracomplex heterocyclic compounds, zene and (N Si) trifluoro(2-aminoethoxy)silane

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Doklady Chemistry – Springer Journals

Published: Aug 17, 2006

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