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Xuesong Jiang, Hongjie Xu, Jie Yin (2005)
Copolymeric dendritic macrophotoinitiatorsPolymer, 46
K Dietliker (1991)
Chemistry & Technology of UV & EB Formulation for Coatings, Inks & Paints
Burcu Oktay, Serap Demir, Nilhan Kayaman‐Apohan (2015)
Immobilization of α-amylase onto poly(glycidyl methacrylate) grafted electrospun fibers by ATRP.Materials science & engineering. C, Materials for biological applications, 50
I. Clemente, M. Aznar, C. Nerín, Osvaldo Bosetti (2016)
Migration from printing inks in multilayer food packaging materials by GC-MS analysis and pattern recognition with chemometricsFood Additives & Contaminants: Part A, 33
S. Yamago, Eiichi Kayahara, Hiroto Yamada (2009)
Synthesis of structurally well-controlled ω-vinylidene functionalized poly(alkyl methacrylate)s and polymethacrylonitrile by organotellurium, organostibine, and organobismuthine-mediated living radical polymerizationsReactive & Functional Polymers, 69
Gokhan Temel, N. Arsu, Y. Yagcı (2006)
Polymeric Side Chain Thioxanthone Photoinitiator for Free Radical PolymerizationPolymer Bulletin, 57
W. Braunecker, K. Matyjaszewski (2007)
Controlled/living radical polymerization: Features, developments, and perspectivesProgress in Polymer Science, 32
R Meuwly (2011)
Packaging Materials 8. Printing Inks for Food Packaging Composition and Properties of Printing Inks
Krzysztof Matyjaszewski (2006)
Controlled/Living Radical Polymerization: From Synthesis to Materials
Meral Aydın, N. Arsu, Y. Yagcı, S. Jockusch, N. Turro (2005)
Mechanistic Study of Photoinitiated Free Radical Polymerization Using Thioxanthone Thioacetic Acid as One-Component Type II PhotoinitiatorMacromolecules, 38
T. Rothenbacher, M. Baumann, D. Fügel (2007)
2-Isopropylthioxanthone (2-ITX) in food and food packaging materials on the German marketFood Additives & Contaminants, 24
H. Akat, B. Gacal, D. Balta, N. Arsu, Y. Yagcı (2010)
Poly(ethylene glycol)‐thioxanthone prepared by Diels–Alder click chemistry as one‐component polymeric photoinitiator for aqueous free‐radical polymerizationJournal of Polymer Science Part A, 48
Aslı Beyler-Çiğil, M. Kahraman (2016)
Effect of surface modification on nano-diamond particles for surface and thermal property of UV-curable hybrid coatingProgress in Organic Coatings, 101
C. Smith, H. Grubbs, H. Webster, A. Gungör, J. Wightman, J. Mcgrath (1991)
Unique Characteristics Derived From Poly(Arylene Ether Phosphine Oxide)sHigh Performance Polymers, 3
citation_title= (1969)
1969 Methods of test for printing inks (resistance of prints to various physical and chemical agents)_Status: Superseded, Withdrawn
Xuesong Jiang, Jie Yin (2004)
Study of macrophotoinitiator containing in-chain thioxanthone and coinitiator aminesPolymer, 45
Lerzan Cokbaglan, N. Arsu, Y. Yagcı, S. Jockusch, N. Turro (2003)
2-Mercaptothioxanthone as a Novel Photoinitiator for Free Radical PolymerizationMacromolecules, 36
J. Fouassier (1995)
Photoinitiation, photopolymerization, and photocuring
Xuesong Jiang, Jie Yin (2004)
Copolymeric photoinitiators containing in-chain thioxanthone and coinitiator amine for photopolymerizationJournal of Applied Polymer Science, 94
R. Paseiro-Cerrato, A. Quirós, R. Séndon, J. Bustos, J. Sánchez, J. López-Hernández, P. Paseiro-Losada (2015)
Instability of an aromatic amine in fatty food and fatty food simulant: characterisation of reaction products and prediction of their toxicityFood Additives & Contaminants: Part A, 32
D. Avci, T. Eren (2018)
Chapter 4:Monomeric and Polymeric Photoinitiators
Meral Aydın, N. Arsu, Y. Yagcı (2003)
One-Component Bimolecular Photoinitiating Systems, 2†Macromolecular Rapid Communications, 24
Xuesong Jiang, Jie Yin (2004)
Polymeric Photoinitiator Containing In‐Chain Thioxanthone and Coinitiator AminesMacromolecular Rapid Communications, 25
T. Eren, B. Graff, J. Lalevée, D. Avci (2019)
Thioxanthone-functionalized 1,6-heptadiene as monomeric photoinitiatorProgress in Organic Coatings
Xuesong Jiang, Jie Yin (2004)
Dendritic Macrophotoinitiator Containing Thioxanthone and Coinitiator AmineMacromolecules, 37
M. Mishra, Y. Yagcı (1998)
Handbook of Radical Vinyl Polymerization
(1997)
Ph. D. Thesis,
Xuesong Jiang, Jue Luo, Jie Yin (2009)
A novel amphipathic polymeric thioxanthone photoinitiatorPolymer, 50
E. Kandırmaz, N. Apohan, E. Gençoğlu (2018)
Preparation of novel thioxanthone based polymeric photoinitiator for flexographic varnish and determination of their migration behaviourProgress in Organic Coatings
Sajjad Dadashi-Silab, Cansu Aydogan, Y. Yagcı (2015)
Shining a light on an adaptable photoinitiator: advances in photopolymerizations initiated by thioxanthonesPolymer Chemistry, 6
D. Ciofini, J. Striová, M. Camaiti, S. Siano (2016)
Photo-oxidative kinetics of solvent and oil-based terpenoid varnishesPolymer Degradation and Stability, 123
K. Davis, K. Matyjaszewski (2002)
Statistical, Gradient, Block and Graft Copolymers by Controlled/Living Radical Polymerizations
Xuesong Jiang, Hongjie Xu, Jie Yin (2004)
Polymeric amine bearing side-chain thioxanthone as a novel photoinitiator for photopolymerizationPolymer, 45
V. Coessens, T. Pintauer, K. Matyjaszewski (2001)
Functional polymers by atom transfer radical polymerizationProgress in Polymer Science, 26
Jun Wei, Hongyu Wang, Xuesong Jiang, Jie Yin (2006)
Effect on Photopolymerization of the Structure of Amine Coinitiators Contained in Novel Polymeric Benzophenone PhotoinitiatorsMacromolecular Chemistry and Physics, 207
K. Matyjaszewski (1997)
Mechanistic and synthetic aspects of atom transfer radical polymerizationJournal of Macromolecular Science, Part A, 34
K. Matyjaszewski, J. Xia (2001)
Atom transfer radical polymerization.Chemical reviews, 101 9
S P Pappas (1978)
UV Curing Science and Technolgy
R S Davidson (1999)
Exploring the Science, Technology and Applications of UV and EB Curing
Gokhan Temel, N. Arsu (2009)
One-pot synthesis of water-soluble polymeric photoinitiator via thioxanthonation and sulfonation processJournal of Photochemistry and Photobiology A-chemistry, 202
K. Dietliker, R. Hüsler, Jean-Luc Birbaum, S. Ilg, S. Villeneuve, Katia Studer, T. Jung, J. Benkhoff, Hisatoshi Kura, A. Matsumoto, H. Oka (2007)
Advancements in photoinitiators : Opening up new applications for radiation curingProgress in Organic Coatings, 58
Z. Akdemir, Nilhan Kayaman‐Apohan, M. Kahraman, S. Kuruca, A. Güngör, S. Karadenizli (2011)
Preparation of Biocompatible, UV-Cured Fumarated Poly(ether-ester)-Based Tissue-Engineering HydrogelsJournal of Biomaterials Science, Polymer Edition, 22
Abstract Polymeric photoinitiators are widely used in ultraviolet (UV)-curable printing inks because of their low migration behavior. In this study, a new phenylphosphine oxide-polystyrene-thioxanthone (PPO-PSt-TX) polymeric photoinitiator was synthesized. Bis[(4-hydroxy)phenyl]phenyl phosphine oxide (BHPPO) that was synthesized by Grignard technique, was functionalized with 2-bromopropionyl bromide (atom transfer radical polymerization (ATRP) initiator) and then used in styrene polymerization. The bromine end-capped polystyrene was then reacted with 2-thioxanthone-thioacetic acid and final polymeric photoinitiator PPO-PSt-TX was obtained. Proton nuclear magnetic resonance (1H NMR), attenuated total reflectance- Fourier transform infrared spectroscopy (ATR-FTIR), gel permeation chromatography (GPC) and ultraviolet-visible spectroscopy (UV-Vis) confirmed the obtained structure. The curing characteristic of PPO-PSt-TX was compared with a standard flexographic printing varnish formulation containing thioxanthone (TX). The photopolymerization kinetics were determined by photo differential scanning calorimetry (Photo-DSC). The conversion of methylmethacrylate polymerization by using macrophotoinitiator is 78%. The migration behavior of PPO-PSt-TX was identified with liquid chromatography-mass spectrometry (LC-MS). It was shown that PPOPSt- TX macro photoinitiator is suitable for flexographic varnish and the migration level of photoinitiator is reduced by using polymeric photoinitiator.
"Macromolecular Research" – Springer Journals
Published: Aug 1, 2019
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