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ISSN 00125008, Doklady Chemistry, 2013, Vol. 451, Part 1, pp. 191–195. © Pleiades Publishing, Ltd., 2013. Original Russian Text © V.S. Dorokhov, D.I. Ishutenko, P.A. Nikul’shin, O.L. Eliseev, N.N. Rozhdestvenskaya, V.M. Kogan, A.L. Lapidus, 2013, published in Doklady Akademii Nauk, 2013, Vol. 451, No. 3, pp. 291–295. CHEMISTRY The Mechanism of Synthesis Gas Conversion to Alcohols Catalyzed by Transition Metal Sulfides a b b a V. S. Dorokhov , D. I. Ishutenko , P. A. Nikul’shin , O. L. Eliseev , N. N. Rozhdestvenskaya, a a V. M. Kogan , and Corresponding Member of the RAS A. L. Lapidus Received January 31, 2013 DOI: 10.1134/S0012500813070057 The catalysts based on ZnCu or ZnCr oxides and hydrocarbons catalyzed by sulfided K–Co–Mo cata reduced Co that are used to synthesize alcohols and lysts, we became able to explain the promotory effect hydrocarbons from synthesis gas [1, 2] are highly sen of potassium in these systems, which was observed sitive to sulfur impurity [3] and require that the feed be experimentally in our and other researchers' works purified down to sulfur contents of several ppb. The [11–13]. The general regularities of operation of the use of catalysts based on alkali metalmodified molyb active
Doklady Chemistry – Springer Journals
Published: Aug 7, 2013
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