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In anaerobic methanogenic sediment microcosms14C labelled chloroform was degraded mainly to carbon dioxide. At a concentration of 4 μg.l−1 the mineralization followed first order kinetics with a half life of 12 days at 10°C and 2.6 days at 20°C. At a concentration of 400 μg.l−1 the mineralization rate increased with time and followed logarithmic kinetics with a μmax of 0.02.d−1 at 10°C. The logarithmic kinetics can be explained by growth of the bacteria on the higher concentration of chloroform with a generation time of 35 days. Shaking and oxygenation did not inhibit the mineralization of chloroform, probably because of bacterial consumption of the dissolved oxygen.
Aquatic Ecology – Springer Journals
Published: Nov 4, 2005
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