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In this paper we study an asymmetric valley-ridge inflection point (VRI) potential, whose energy surface (PES) features two sequential index-1 saddles (the upper and the lower), with one saddle havinghigher energy than the other, and two potential wells separated by the lower index-1 saddle. We show how the depth and the flatness of our potential changes as we modify the parameter that controls the asymmetry as well as how the branching ratio (ratio of the trajectories that enter each well) is changing as we modify the same parameter and its correlation with the area of the lobes as they have been formedby the stableand unstable manifolds that have been extracted from the gradient of the LD scalar fields.
Regular and Chaotic Dynamics – Springer Journals
Published: Mar 1, 2022
Keywords: phase space structure; Lagrangian descriptors; chemical reaction dynamics; valley ridge inflection point potential
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