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The effect of alumina addition on the conductivity, microstructure and mechanical strength of zirconia — yttria electrolytes

The effect of alumina addition on the conductivity, microstructure and mechanical strength of... The effect of alumina additions on the ionic conductivity and mechanical properties of 3 and 8 mol% Y2O3 - ZrO2 compositions has been investigated. Such materials are of interest for use in fuel cells and other similar applications. Sintered specimens were characterised by XRD, SEM, impedance spectroscopy, four — probe DC conductivity and mechanical strength measurements. Alumina additions had no affect on the conductivity degradation behaviour at 1000 °C and the activation energy but resulted in an increase in the strength of 8 mol% Y2O3 - ZrO2 composition by about 25%. However, a significant drop in the ionic conductivity well above what could be accounted for by the decrease in the volume fraction of the conducting phase, was observed. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Ionics Springer Journals

The effect of alumina addition on the conductivity, microstructure and mechanical strength of zirconia — yttria electrolytes

Ionics , Volume 4 (2) – Mar 21, 2006

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References (14)

Publisher
Springer Journals
Copyright
Copyright © 1998 by IfI - Institute for Ionics
Subject
Chemistry; Biomedicine general; Analytical Chemistry; Physical Chemistry; Electrochemistry; Optical and Electronic Materials
ISSN
0947-7047
eISSN
1862-0760
DOI
10.1007/BF02375776
Publisher site
See Article on Publisher Site

Abstract

The effect of alumina additions on the ionic conductivity and mechanical properties of 3 and 8 mol% Y2O3 - ZrO2 compositions has been investigated. Such materials are of interest for use in fuel cells and other similar applications. Sintered specimens were characterised by XRD, SEM, impedance spectroscopy, four — probe DC conductivity and mechanical strength measurements. Alumina additions had no affect on the conductivity degradation behaviour at 1000 °C and the activation energy but resulted in an increase in the strength of 8 mol% Y2O3 - ZrO2 composition by about 25%. However, a significant drop in the ionic conductivity well above what could be accounted for by the decrease in the volume fraction of the conducting phase, was observed.

Journal

IonicsSpringer Journals

Published: Mar 21, 2006

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