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The constancy of the concentration of an inhibitor preventing the ignition of gases

The constancy of the concentration of an inhibitor preventing the ignition of gases Mechanisms of consumption of inhibitors in gas mixtures in different combustion modes—ignition prevention and suppression of flame propagation and detonation—have been revealed. It has been found that no more than a few hundredths of a percent of the initial reagents, including the inhibitor, are consumed for the prevention of ignition. In suppression of flame propagation and detonation, the inhibitor is consumed only in chain termination reactions. Oxygen is additionally consumed only in reactions with the products of incomplete oxidation of the inhibitor. The results have been interpreted in the framework of the theory of nonisothermal chain processes. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Doklady Chemistry Springer Journals

The constancy of the concentration of an inhibitor preventing the ignition of gases

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References (4)

Publisher
Springer Journals
Copyright
Copyright © 2016 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
0012-5008
eISSN
1608-3113
DOI
10.1134/S0012500816020014
Publisher site
See Article on Publisher Site

Abstract

Mechanisms of consumption of inhibitors in gas mixtures in different combustion modes—ignition prevention and suppression of flame propagation and detonation—have been revealed. It has been found that no more than a few hundredths of a percent of the initial reagents, including the inhibitor, are consumed for the prevention of ignition. In suppression of flame propagation and detonation, the inhibitor is consumed only in chain termination reactions. Oxygen is additionally consumed only in reactions with the products of incomplete oxidation of the inhibitor. The results have been interpreted in the framework of the theory of nonisothermal chain processes.

Journal

Doklady ChemistrySpringer Journals

Published: Apr 1, 2016

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