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Synthesis, Structure, and Magnetic Properties of the Tetranuclear Cluster of Monovalent Nickel {[(Ph3P)Ni(μ2-Cl)]4[μ2,η2-PhC≡CPh]2}

Synthesis, Structure, and Magnetic Properties of the Tetranuclear Cluster of Monovalent Nickel... Doklady Chemistry, Vol. 403, Part 1, 2005, pp. 136–139. Translated from Doklady Akademii Nauk, Vol. 403, No. 3, 2005, pp. 345–348. Original Russian Text Copyright © 2005 by Sushev, Kornev, Shvedenkov, Kurskii, Fukin, Baranov, Abakumov. CHEMISTRY Synthesis, Structure, and Magnetic Properties of the Tetranuclear Cluster of Monovalent Nickel {[(Ph P)Ni(m -Cl)] [m ,h -PhC∫CPh] } 3 2 4 2 2 V. V. Sushev*, A. N. Kornev*, Yu. G. Shvedenkov**, Yu. A. Kurskii*, G. K. Fukin*, E. V. Baranov*, and Academician G. A. Abakumov* Received April 11, 2005 Nickel complexes are known to be prone to the for- proportionation to Ni(0) and Ni(II) under the action of mation of associates and cluster-type compounds [1]. carbon monoxide is noteworthy. As one of the products, Clusters exhibit radically different physicochemical the zerovalent nickel complex (Ph P) Ni(CO) was iso- 3 2 2 properties than their constituting monomeric units. It is lated, which gave rise to a P NMR signal at 34 ppm. of great interest to study both the chemical properties of Unit cell parameters were refined and reflection clusters and the exchange coupling between their con- intensities were collected on a Bruker AXS Smart Apex stituting paramagnetic centers. However, as distinct http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Doklady Chemistry Springer Journals

Synthesis, Structure, and Magnetic Properties of the Tetranuclear Cluster of Monovalent Nickel {[(Ph3P)Ni(μ2-Cl)]4[μ2,η2-PhC≡CPh]2}

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References (8)

Publisher
Springer Journals
Copyright
Copyright © 2005 by MAIK “Nauka/Interperiodica”
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
0012-5008
eISSN
1608-3113
DOI
10.1007/s10631-005-0055-9
Publisher site
See Article on Publisher Site

Abstract

Doklady Chemistry, Vol. 403, Part 1, 2005, pp. 136–139. Translated from Doklady Akademii Nauk, Vol. 403, No. 3, 2005, pp. 345–348. Original Russian Text Copyright © 2005 by Sushev, Kornev, Shvedenkov, Kurskii, Fukin, Baranov, Abakumov. CHEMISTRY Synthesis, Structure, and Magnetic Properties of the Tetranuclear Cluster of Monovalent Nickel {[(Ph P)Ni(m -Cl)] [m ,h -PhC∫CPh] } 3 2 4 2 2 V. V. Sushev*, A. N. Kornev*, Yu. G. Shvedenkov**, Yu. A. Kurskii*, G. K. Fukin*, E. V. Baranov*, and Academician G. A. Abakumov* Received April 11, 2005 Nickel complexes are known to be prone to the for- proportionation to Ni(0) and Ni(II) under the action of mation of associates and cluster-type compounds [1]. carbon monoxide is noteworthy. As one of the products, Clusters exhibit radically different physicochemical the zerovalent nickel complex (Ph P) Ni(CO) was iso- 3 2 2 properties than their constituting monomeric units. It is lated, which gave rise to a P NMR signal at 34 ppm. of great interest to study both the chemical properties of Unit cell parameters were refined and reflection clusters and the exchange coupling between their con- intensities were collected on a Bruker AXS Smart Apex stituting paramagnetic centers. However, as distinct

Journal

Doklady Chemistry – Springer Journals

Published: Aug 1, 2005

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