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Lijun Chen, Feng Wu (2012)
Properties of polyacrylate latex prepared under different emulsified systemsJournal of Wuhan University of Technology-Mater. Sci. Ed., 27
Jun Luo, Qing Wu, Hengchao Huang, Jian-jun Chen (2011)
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(2014)
Polym
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Lijun Chen, Feng Wu (2012)
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Xinyan Xiao, Ye Wang (2009)
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Water and oil-repellent coatings of perfluoro-polyacrylate resins on cotton fibers: UV curing in comparison with thermal polymerizationFibers and Polymers, 13
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Lifen Hao, Qiu-feng An, W. Xu (2012)
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Abstract Fluorinated polyacrylate latexes are preferably candidates for the textile water repellent finishes as a result of their special surface property and especially economical, low-toxic characteristics compared to fluorinated polyacrylate solutions. The benefits of soap-free latex prepared from reactive surfactants are now well known. We herein used a reactive emulsifier, ammonium allyloxtmethylate nonylphenol ethoxylates sulfate (DNS-86), to prepare novel self-crosslinking fluorinecontaining polyacrylate soap-free latex (FMBN) with core-shell structure by co-polymerization of dodecafluoroheptyl methacrylate (DFMA), methyl methacrylate (MMA), butyl acrylate (BA), and N-methylolamide (NMA), and then treated the cotton fabric with FMBN. Results showed that the as-prepared latex particles had the uniform spherical core-shell structure with an average diameter of 116 nm. FMBN could form a smooth resin film on the treated fabric/fiber surface under Field emission scanning electron microscopy (FESEM) observation, but some protuberances appeared on that surface from Atomic force microscopy (AFM) image. X-ray photoelectron spectroscopy (XPS) analysis indicated the fluoroalkyl groups tended to enrich at the film-air interface. Hydrophobicity of the FMBN treated fabric was superior to that of the fabrics treated by general emulsion and the non-crosslinking one. In addition, the above three latexes didn’t influence whiteness of the treated fabrics at all. However, they all, and in especial two self-crosslinking latexes would make the treated fabrics stiffer compared to non-crosslinking one.
Fibers and Polymers – Springer Journals
Published: Mar 1, 2014
Keywords: Polymer Sciences
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