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Yuan Xue, Zhen-bo Wang, Li-Li Zheng, Fu‐da Yu, Bao-sheng Liu, Yin Zhang, Yu-Xiang Zhou (2015)
Synthesis and performance of hollow LiNi0.5Mn1.5O4 with different particle sizes for lithium-ion batteriesRSC Advances, 5
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Polyhedral LiNi0.5Mn1.5O4 with excellent electrochemical properties for lithium-ion batteriesJournal of Materials Chemistry, 2
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Nanosized LiNi0.5Mn1.5O4 spinels synthesized by a high-oxidation-state manganese sol–gel methodIonics, 19
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Estimation on diffusion coefficient of lithium ions at the interface of LiNi0.5Mn1.5O4/electrolyte in Li-ion batteryIonics, 21
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Effects of different precipitants on LiNi0.5Mn1.5O4 for lithium ion batteries prepared by modified co-precipitation methodIonics, 23
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High-voltage spinel LiNi0.5Mn1.5O4 nano/microspheres with adjustable hollow structures have been fabricated based on the Kirkendall effect. The main characteristic is that the wall thickness of the hollow structure as well as the cavity size of the hollow structure can be adjusted by the different ratio of mixed precipitation agents. Especially, the diagrammatic sketch for the formation process of various LiNi0.5Mn1.5O4 materials with adjustable hollow structures is discussed. Besides, the results of electrochemical performance test show that LiNi0.5Mn1.5O4 obtained from 10:1 Na2CO3/NaOH (in mole) ratio is worth looking forward to, owing to its special hierarchical nano/microsphere and moderate hollow structures.
Ionics – Springer Journals
Published: Aug 21, 2017
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