Access the full text.
Sign up today, get DeepDyve free for 14 days.
Loading next page...
/lp/springer-journals/synthesis-ir-spectra-and-structures-of-double-metaphosphates-m-ni-po-3-t3JvVIQHtr
References (5)
-
M. Laügt, M. Scory, A. Durif (1968)
Etude des systemes Cu(PO3)2/1bTlPO3 et Cu(PO3)2/1bRbPO3 donnees cristallographiques sur CuTl(PO3)3 et CuRb(PO3)3Materials Research Bulletin, 3
-
I. V. Pyatnitskii (1969)
Analytical Chemistry -
G. E. F. Lundell (1953)
Applied Inorganic Analysis with Special Reference to the Analysis of Metals, Minerals and Rocks -
V. A. Masloboev (1989)
Rare Earth Phosphates -
C. Martin, A. Mitschler (1972)
Structure cristalline du trimétaphosphate de baryum–sodium: BaNaP3O9Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, 28
- Publisher
- Springer Journals
- Copyright
- 2000 MAIK "Nauka/Interperiodica"
- ISSN
- 1063-7745
- eISSN
- 1562-689X
- DOI
- 10.1134/1.171164
- Publisher site
- See Article on Publisher Site
Abstract
Abstract Double metaphosphates of the composition MNi(PO3)3 (M = Na or K) were prepared by spontaneous crystallization from melts in the M 2O-P2O5-NiO system. Their thermal properties were studied, and the IR spectra were analyzed. The complete X-ray structure analysis of the compounds synthesized was performed. The NaNi(PO3)3 crystals are orthorhombic with the unit-cell parameters a = 13.781(2) Å, b = 10.584(2) Å, c = 9.873(1) Å, sp. gr. Pcca. The KNi(PO3)3 crystals belong to the sp. gr. R3 with the unit-cell parameters a = 10.076(2) Å and c = 9.623(5) Å. The structures of the studied phosphates are compared with the structures of the related compounds.
Journal
Crystallography Reports – Springer Journals
Published: Mar 1, 2000