Get 20M+ Full-Text Papers For Less Than $1.50/day. Start a 14-Day Trial for You or Your Team.

Learn More →

Synthesis, Crystal Structure, FT-IR Spectral Studies and Hirshfeld Surface Analysis of 3-Amino-5,6-dimethyl-1,2,4-triazine/3-Amino-5,6-dimethyl-1,2,4-triazinium-2 2-hydroxybenzoate and 3-Amino-5,6-dimethyl-1,2,4-triazinium-2 hydrogen phthalate

Synthesis, Crystal Structure, FT-IR Spectral Studies and Hirshfeld Surface Analysis of... Abstract The title molecular salts (C5H9N\(_{4}^{ + }\))(C5H8N4)(C7H5O\(_{3}^{ - }\)) (I) and (C5H9N\(_{4}^{ + }\))(C8H5O\(_{4}^{ - }\)) (II) have been synthesized and characterized by single crystal X-ray diffraction, FT-IR and Hirshfeld surface analysis. I crystallizes in monoclinic system, sp. gr. P21/c, Z = 4. II crystallizes in triclinic system, sp. gr. P\(\bar {1}\), Z = 2. Both crystal structures are stabilized by N–H···O, N–H···N, O–H···O hydrogen bonds and weak π–π stacking interactions and form a ring motifs (\(R_{2}^{2}\)(8)) containing N+–H···O– charge-assisted hydrogen bonds. FT-IR spectra confirm the presence of the functional groups in the synthesized compounds. Hirshfeld surface analysis was employed in order to study intermolecular interactions. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Crystallography Reports Springer Journals

Synthesis, Crystal Structure, FT-IR Spectral Studies and Hirshfeld Surface Analysis of 3-Amino-5,6-dimethyl-1,2,4-triazine/3-Amino-5,6-dimethyl-1,2,4-triazinium-2 2-hydroxybenzoate and 3-Amino-5,6-dimethyl-1,2,4-triazinium-2 hydrogen phthalate

Crystallography Reports , Volume 63 (6): 9 – Nov 1, 2018

Loading next page...
 
/lp/springer-journals/synthesis-crystal-structure-ft-ir-spectral-studies-and-hirshfeld-SGkXqdppuz

References (18)

Publisher
Springer Journals
Copyright
2018 Pleiades Publishing, Inc.
ISSN
1063-7745
eISSN
1562-689X
DOI
10.1134/S1063774518060263
Publisher site
See Article on Publisher Site

Abstract

Abstract The title molecular salts (C5H9N\(_{4}^{ + }\))(C5H8N4)(C7H5O\(_{3}^{ - }\)) (I) and (C5H9N\(_{4}^{ + }\))(C8H5O\(_{4}^{ - }\)) (II) have been synthesized and characterized by single crystal X-ray diffraction, FT-IR and Hirshfeld surface analysis. I crystallizes in monoclinic system, sp. gr. P21/c, Z = 4. II crystallizes in triclinic system, sp. gr. P\(\bar {1}\), Z = 2. Both crystal structures are stabilized by N–H···O, N–H···N, O–H···O hydrogen bonds and weak π–π stacking interactions and form a ring motifs (\(R_{2}^{2}\)(8)) containing N+–H···O– charge-assisted hydrogen bonds. FT-IR spectra confirm the presence of the functional groups in the synthesized compounds. Hirshfeld surface analysis was employed in order to study intermolecular interactions.

Journal

Crystallography ReportsSpringer Journals

Published: Nov 1, 2018

There are no references for this article.