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Synthesis, Crystal Structure, and Vibrational Spectra of an Azomethine Derivativeof Benzo-15-crown-5, N-(4′-Benzo-15-crown-5)-2-(amino-N-tosyl)phenylaldimine

Synthesis, Crystal Structure, and Vibrational Spectra of an Azomethine Derivativeof... Doklady Chemistry, Vol. 398, Part 1, 2004, pp. 179–183. Translated from Doklady Akademii Nauk, Vol. 398, No. 1, 2004, pp. 62–67. Original Russian Text Copyright © 2004 by Minacheva, Ivanova, Dorokhov, Bicherov, Burlov, Garnovskii, Sergienko, Tsivadze. CHEMISTRY Synthesis, Crystal Structure, and Vibrational Spectra of an Azomethine Derivativeof Benzo-15-crown-5, N-(4'-Benzo-15-crown-5)-2-(amino-N-tosyl)phenylaldimine L. Kh. Minacheva*, I. S. Ivanova*, A. V. Dorokhov*, A. V. Bicherov**, A. S. Burlov**, A. D. Garnovskii**, V. S. Sergienko*, and Academician A. Yu. Tsivadze*** Received May 24, 2004 Considerable recent attention has been focused on In this paper, we report on the synthesis, the vibra- crown ether derivatives containing different chro- tional spectra, and the results of X-ray diffraction analysis mophore groups (see, e.g., [1–3]). These compounds of N-(4'-benzo-15-crown-5)-2-(amino-N-tosyl)phenyl- are used in analytical chemistry as photometric aldimine (I), a benzo-15-crown-5 derivative containing an azomethine fragment. reagents for determination of metals and as extractants [4] and in supramolecular chemistry (cation receptors, Compound I was synthesized by the following pro- photoswitches, photosensible molecular antennas) cedure: A solution of 0.283 g of 4-aminobenzo-15- [5, 6]. However, crown ether derivatives with an crown-5 in 5 mL of benzene was added to a solution of azomethine fragment C=N– have not heretofore been 0.275 http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Doklady Chemistry Springer Journals

Synthesis, Crystal Structure, and Vibrational Spectra of an Azomethine Derivativeof Benzo-15-crown-5, N-(4′-Benzo-15-crown-5)-2-(amino-N-tosyl)phenylaldimine

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References (4)

Publisher
Springer Journals
Copyright
Copyright © 2004 by MAIK “Nauka/Interperiodica”
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
0012-5008
eISSN
1608-3113
DOI
10.1023/B:DOCH.0000041483.77617.47
Publisher site
See Article on Publisher Site

Abstract

Doklady Chemistry, Vol. 398, Part 1, 2004, pp. 179–183. Translated from Doklady Akademii Nauk, Vol. 398, No. 1, 2004, pp. 62–67. Original Russian Text Copyright © 2004 by Minacheva, Ivanova, Dorokhov, Bicherov, Burlov, Garnovskii, Sergienko, Tsivadze. CHEMISTRY Synthesis, Crystal Structure, and Vibrational Spectra of an Azomethine Derivativeof Benzo-15-crown-5, N-(4'-Benzo-15-crown-5)-2-(amino-N-tosyl)phenylaldimine L. Kh. Minacheva*, I. S. Ivanova*, A. V. Dorokhov*, A. V. Bicherov**, A. S. Burlov**, A. D. Garnovskii**, V. S. Sergienko*, and Academician A. Yu. Tsivadze*** Received May 24, 2004 Considerable recent attention has been focused on In this paper, we report on the synthesis, the vibra- crown ether derivatives containing different chro- tional spectra, and the results of X-ray diffraction analysis mophore groups (see, e.g., [1–3]). These compounds of N-(4'-benzo-15-crown-5)-2-(amino-N-tosyl)phenyl- are used in analytical chemistry as photometric aldimine (I), a benzo-15-crown-5 derivative containing an azomethine fragment. reagents for determination of metals and as extractants [4] and in supramolecular chemistry (cation receptors, Compound I was synthesized by the following pro- photoswitches, photosensible molecular antennas) cedure: A solution of 0.283 g of 4-aminobenzo-15- [5, 6]. However, crown ether derivatives with an crown-5 in 5 mL of benzene was added to a solution of azomethine fragment C=N– have not heretofore been 0.275

Journal

Doklady ChemistrySpringer Journals

Published: Dec 29, 2004

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