Access the full text.
Sign up today, get DeepDyve free for 14 days.
Xiaming Feng, Xin Wang, Wei Cai, Ningning Hong, Yuan Hu, K. Liew (2016)
Integrated effect of supramolecular self-assembled sandwich-like melamine cyanurate/MoS2 hybrid sheets on reducing fire hazards of polyamide 6 composites.Journal of hazardous materials, 320
Li-Kun Xiong, Yifan Fu, Shouzhi Zhang, Cuiyu Yin (2016)
Investigation of stain-resistant cationic dyeable nylon 6 modified with sodium salt of 5-sulfoisophthalic acid and polyethylene glycolFibers and Polymers, 17
T. Kashiwagi, R. Harris, Xin Zhang, R. Briber, B. Cipriano, S. Raghavan, W. Awad, J. Shields (2004)
Flame retardant mechanism of polyamide 6–clay nanocomposites ☆Polymer, 45
Mathieu Coquelle, S. Duquesne, M. Casetta, Jun Sun, X. Gu, Sheng Zhang, S. Bourbigot (2015)
Flame Retardancy of PA6 Using a Guanidine Sulfamate/Melamine Polyphosphate MixturePolymers, 7
Ceyda Isbasar, J. Hacaloglu (2012)
Investigation of thermal degradation characteristics of polyamide-6 containing melamine or melamine cyanurate via direct pyrolysis mass spectrometryJournal of Analytical and Applied Pyrolysis, 98
Yinghong Chen, Qi Wang, Wei-Qun Yan, Hong-Mei Tang (2006)
Preparation of flame retardant polyamide 6 composite with melamine cyanurate nanoparticles in situ formed in extrusion processPolymer Degradation and Stability, 91
Yan Shen, S. Wen, Ji Wang, Hong Liu, H. Qi, Qian Xu, W. Hu (2011)
Flame Retardant Polyamide 6 Composites Using NMH or NMH/MCA/APPAdvanced Materials Research, 189-193
Tolibjon Omonov, C. Harrats, N. Moussaif, G. Groeninckx, S. Sadykov, N. Ashurov (2004)
Polyamide 6/ethylene-butylene elastomer blends generated via anionic polymerization of ε-caprolactam: Phase morphology and dynamic mechanical behaviorJournal of Applied Polymer Science, 94
Yanli Liu, Si-Yuan Liu, Cuiyu Yin (2014)
Synthesis and structure–property of polyamide 6/Macrogol/attapulgite nanocompositesPolymer Composites, 35
Li Sun, Jintao Yang, G. Lin, Mingqiang Zhong (2007)
Crystallization and thermal properties of polyamide 6 composites filled with different nanofillersMaterials Letters, 61
K. Sha, Y. Hu, Y. Wang, R. Xiao (2014)
Preparation of flame retardant polyamide 6/melamine cyanurate via in situ polymerisation and its characterisationMaterials Research Innovations, 18
B. Guo, Quanliang Zou, Y. Lei, Mingliang Du, Mingxian Liu, D. Jia (2009)
Crystallization behavior of polyamide 6/halloysite nanotubes nanocompositesThermochimica Acta, 484
Y. Son, Jinpyo Hong, Hyeong-Tae Lim, Tae-Kyung Kim (2005)
A study of heterobifunctional reactive dyes on nylon fibers: dyeing properties, dye moiety analysis and wash fastnessDyes and Pigments, 66
Dan-dan Zhang, Dongqing Liu, Qingjuan Ren, Yingbo Chen, Cuiyu Yin (2016)
Fabrication of polyamide-6 fiber of high SO3H content surface through electrospinningPolymer, 98
Zhixia Wu, Wei Xu, Jinfeng Xia, Yaochi Liu, Q. Wu, Weijian Xu (2008)
Flame retardant polyamide 6 by in situ polymerization of ɛ-caprolactam in the presence of melamine derivativesChinese Chemical Letters, 19
Alvianto Wirasaputra, Lijun Zheng, Shumei Liu, Yanchao Yuan, Jianqing Zhao (2016)
High-Performance Flame-Retarded Polyamide-6 Composite Fabricated by Chain ExtensionMacromolecular Materials and Engineering, 301
Xubing Fu, Chenguang Yao, Guisheng Yang (2015)
Recent advances in graphene/polyamide 6 composites: a reviewRSC Advances, 5
Yuanyuan Li, Yunzhi Lin, K. Sha, R. Xiao (2017)
Preparation and characterizations of flame retardant melamine cyanurate/polyamide 6 composite fibers via in situ polymerizationTextile Research Journal, 87
Yinghong Chen, Qi Wang (2006)
Preparation, properties and characterizations of halogen-free nitrogen–phosphorous flame-retarded glass fiber reinforced polyamide 6 compositePolymer Degradation and Stability, 91
Zi-qi Guo, Chenglei Wang, Juan Li, Q. Yao (2016)
Micro‐intumescent flame retardant polyamide 6 based on cyclic phosphate grafting phenol formaldehydePolymers for Advanced Technologies, 27
Lili Li, Wu Zhihao, Jiang Shuaishuai, Zhang Sideng, S. Lu, Wenping Chen, B. Sun, Meifang Zhu (2015)
Effect of halloysite nanotubes on thermal and flame retardant properties of polyamide 6/melamine cyanurate compositesPolymer Composites, 36
D. Bakirtzis, A. Ramani, Jianping Zhang, M. Delichatsios (2014)
Simplified structure of the condensed phase of fire retarded PA6 nanocomposites in TGA as related flammabilityFire Safety Journal, 69
Zhugen Yang, Zishou Zhang, Y. Tao, K. Mai (2009)
Preparation, crystallization behavior, and melting characteristics of β-nucleated isotactic polypropylene blends with polyamide 6Journal of Applied Polymer Science, 112
S. Huang (2017)
Int. J. Polym. Sci.
Li-Kun Xiong, Cuiyu Yin (2017)
Preparation and characterization of cationic dyeable polycaprolactam modified with 5-sulfoisophthalic acid sodium and poly(ethylene glycol)Textile Research Journal, 87
Chahira Makhlouf, N. Ladhari, S. Roudesli, F. Sakly (2012)
Influence of grafting with acrylic acid on the dyeing properties of polyamide 6.6 fibresColoration Technology, 128
Zhixia Wu, Weixiu Xu, Yaochi Liu, Jinfeng Xia, Q. Wu, Weijian Xu (2009)
Preparation and characterization of flame-retardant melamine cyanurate/polyamide 6 nanocomposites by in situ polymerizationJournal of Applied Polymer Science, 113
A. Yebra-Rodríguez, P. Álvarez-Lloret, A. Rodríguez-Navarro, J. Martin-Ramos, C. Cardell (2009)
Thermo-XRD and differential scanning calorimetry to trace epitaxial crystallization in PA6/montmorillonite nanocompositesMaterials Letters, 63
R. Horrocks, A. Sitpalan, Chen Zhou, B. Kandola (2016)
Flame Retardant Polyamide Fibres: The Challenge of Minimising Flame Retardant Additive Contents with Added NanoclaysPolymers, 8
Abstract Unmodified polyamide 6 commonly dyed with acid dyes, and has no flame-retarded properties. So they are flammable and can be easily stained by foods or drinks that contain acid dyes. However, the acid groups react with amino groups that existed at the end of PA6 chain while using cationic dyes. Thus, the acid dyes can be washed immediately. In this study, the flame retardant and cationic dyeable polyamide 6 (FRCD-PA6) modified with 5-sulfoisophthalic acid sodium (5-SSIPA) and melamine cyanurate (MCA) was successfully prepared by the two-step-melt polymerization method. Firstly, cationic dyeable polyamide 6 (CD-PA6) was prepared with sodium salt from 5-sulfoisphthalic acid. Secondly, melamine cyanurate, as an efficient flame retardant, was blended into the reaction. The chemical and crystalline structures of FRCDPA6 were characterized by the Fourier transform infrared spectroscopy (FT-IR) and wide angle X-ray diffraction (XRD). Their thermal properties were tested by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA), and morphology was analyzed by SEM, respectively. It had been measured to prove the dispersion of 5-SSIPA and MCA on polyamide 6 matrix. Incorporating with 5-SSIPA created more amorphous regions and rose up the dyeing rate easily, with a highest dyeing rate for about 96.79 %. The effect of varying MCA content on the composites showed more flame retardant and made better heat-resistance. Moreover, with the appropriate addition of MCA content, the limit oxygen index (LOI) reached up to 27, less smoking, no more black smoke, droplet phenomenon was slightly, and flame resistance had greatly improved. Because of the good synergy between 5-SSIPA and MCA, a kind of novel modified polyamide 6 which own both cationic dyeable and efficient flame retardant properties was born.
Fibers and Polymers – Springer Journals
Published: Jul 1, 2018
Keywords: Polymer Sciences
Read and print from thousands of top scholarly journals.
Already have an account? Log in
Bookmark this article. You can see your Bookmarks on your DeepDyve Library.
To save an article, log in first, or sign up for a DeepDyve account if you don’t already have one.
Copy and paste the desired citation format or use the link below to download a file formatted for EndNote
Access the full text.
Sign up today, get DeepDyve free for 14 days.
All DeepDyve websites use cookies to improve your online experience. They were placed on your computer when you launched this website. You can change your cookie settings through your browser.