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Synthesis and Structure of New Glutarate-Containing U(VI), Np(V), and Pu(VI) Compounds

Synthesis and Structure of New Glutarate-Containing U(VI), Np(V), and Pu(VI) Compounds The structures of three new glutarate-containing compounds have been characterized. These compounds are (CN3H6)2[(UO2)2(C5H6O4)3] · 4H2O (I), (CN3H6)4[(NpO2)2(C5H6O4)3] · 12H2O (II), and [PuO2(C5H6O4)(H2O)] (III), where C5H6O\documentclass[12pt]{minimal}\usepackage{amsmath}\usepackage{wasysym}\usepackage{amsfonts}\usepackage{amssymb}\usepackage{amsbsy}\usepackage{mathrsfs}\usepackage{upgreek}\setlength{\oddsidemargin}{-69pt}\begin{document}$$_{4}^{{2 - }}$$\end{document} are glutarate anions and CN3H\documentclass[12pt]{minimal}\usepackage{amsmath}\usepackage{wasysym}\usepackage{amsfonts}\usepackage{amssymb}\usepackage{amsbsy}\usepackage{mathrsfs}\usepackage{upgreek}\setlength{\oddsidemargin}{-69pt}\begin{document}$$_{6}^{ + }$$\end{document} are guanidium cations. It was established that the structures of crystals I and II contain [(AnO2)2(C5H6O4)3]z– layers (An = U(VI) or Np(V) and z = 2 or 4, respectively), which can be described by the A2Q\documentclass[12pt]{minimal}\usepackage{amsmath}\usepackage{wasysym}\usepackage{amsfonts}\usepackage{amssymb}\usepackage{amsbsy}\usepackage{mathrsfs}\usepackage{upgreek}\setlength{\oddsidemargin}{-69pt}\begin{document}$$_{3}^{{02}}$$\end{document} crystallochemical formula, where A is UO\documentclass[12pt]{minimal}\usepackage{amsmath}\usepackage{wasysym}\usepackage{amsfonts}\usepackage{amssymb}\usepackage{amsbsy}\usepackage{mathrsfs}\usepackage{upgreek}\setlength{\oddsidemargin}{-69pt}\begin{document}$$_{2}^{{2 + }}$$\end{document} or NpO\documentclass[12pt]{minimal}\usepackage{amsmath}\usepackage{wasysym}\usepackage{amsfonts}\usepackage{amssymb}\usepackage{amsbsy}\usepackage{mathrsfs}\usepackage{upgreek}\setlength{\oddsidemargin}{-69pt}\begin{document}$$_{2}^{ + }$$\end{document} and Q02 are glutarate ions. The structure of crystal III contains two interpenetrating [PuO2(C5H6O4)(H2O)] frameworks and can be described by the AQ21M1 crystallochemical formula, where A = PuO\documentclass[12pt]{minimal}\usepackage{amsmath}\usepackage{wasysym}\usepackage{amsfonts}\usepackage{amssymb}\usepackage{amsbsy}\usepackage{mathrsfs}\usepackage{upgreek}\setlength{\oddsidemargin}{-69pt}\begin{document}$$_{2}^{{2 + }}$$\end{document}, Q21 = C5H6O\documentclass[12pt]{minimal}\usepackage{amsmath}\usepackage{wasysym}\usepackage{amsfonts}\usepackage{amssymb}\usepackage{amsbsy}\usepackage{mathrsfs}\usepackage{upgreek}\setlength{\oddsidemargin}{-69pt}\begin{document}$$_{4}^{{2 - }}$$\end{document}, and М1 = H2O. The influence of topological isomerism on the structures of the glutarate-containing complexes belonging to the A2Q023 and AQ21M1 crystallochemical groups was discussed. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Crystallography Reports Springer Journals

Synthesis and Structure of New Glutarate-Containing U(VI), Np(V), and Pu(VI) Compounds

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References (7)

Publisher
Springer Journals
Copyright
Copyright © Pleiades Publishing, Inc. 2020
ISSN
1063-7745
eISSN
1562-689X
DOI
10.1134/S1063774520010228
Publisher site
See Article on Publisher Site

Abstract

The structures of three new glutarate-containing compounds have been characterized. These compounds are (CN3H6)2[(UO2)2(C5H6O4)3] · 4H2O (I), (CN3H6)4[(NpO2)2(C5H6O4)3] · 12H2O (II), and [PuO2(C5H6O4)(H2O)] (III), where C5H6O\documentclass[12pt]{minimal}\usepackage{amsmath}\usepackage{wasysym}\usepackage{amsfonts}\usepackage{amssymb}\usepackage{amsbsy}\usepackage{mathrsfs}\usepackage{upgreek}\setlength{\oddsidemargin}{-69pt}\begin{document}$$_{4}^{{2 - }}$$\end{document} are glutarate anions and CN3H\documentclass[12pt]{minimal}\usepackage{amsmath}\usepackage{wasysym}\usepackage{amsfonts}\usepackage{amssymb}\usepackage{amsbsy}\usepackage{mathrsfs}\usepackage{upgreek}\setlength{\oddsidemargin}{-69pt}\begin{document}$$_{6}^{ + }$$\end{document} are guanidium cations. It was established that the structures of crystals I and II contain [(AnO2)2(C5H6O4)3]z– layers (An = U(VI) or Np(V) and z = 2 or 4, respectively), which can be described by the A2Q\documentclass[12pt]{minimal}\usepackage{amsmath}\usepackage{wasysym}\usepackage{amsfonts}\usepackage{amssymb}\usepackage{amsbsy}\usepackage{mathrsfs}\usepackage{upgreek}\setlength{\oddsidemargin}{-69pt}\begin{document}$$_{3}^{{02}}$$\end{document} crystallochemical formula, where A is UO\documentclass[12pt]{minimal}\usepackage{amsmath}\usepackage{wasysym}\usepackage{amsfonts}\usepackage{amssymb}\usepackage{amsbsy}\usepackage{mathrsfs}\usepackage{upgreek}\setlength{\oddsidemargin}{-69pt}\begin{document}$$_{2}^{{2 + }}$$\end{document} or NpO\documentclass[12pt]{minimal}\usepackage{amsmath}\usepackage{wasysym}\usepackage{amsfonts}\usepackage{amssymb}\usepackage{amsbsy}\usepackage{mathrsfs}\usepackage{upgreek}\setlength{\oddsidemargin}{-69pt}\begin{document}$$_{2}^{ + }$$\end{document} and Q02 are glutarate ions. The structure of crystal III contains two interpenetrating [PuO2(C5H6O4)(H2O)] frameworks and can be described by the AQ21M1 crystallochemical formula, where A = PuO\documentclass[12pt]{minimal}\usepackage{amsmath}\usepackage{wasysym}\usepackage{amsfonts}\usepackage{amssymb}\usepackage{amsbsy}\usepackage{mathrsfs}\usepackage{upgreek}\setlength{\oddsidemargin}{-69pt}\begin{document}$$_{2}^{{2 + }}$$\end{document}, Q21 = C5H6O\documentclass[12pt]{minimal}\usepackage{amsmath}\usepackage{wasysym}\usepackage{amsfonts}\usepackage{amssymb}\usepackage{amsbsy}\usepackage{mathrsfs}\usepackage{upgreek}\setlength{\oddsidemargin}{-69pt}\begin{document}$$_{4}^{{2 - }}$$\end{document}, and М1 = H2O. The influence of topological isomerism on the structures of the glutarate-containing complexes belonging to the A2Q023 and AQ21M1 crystallochemical groups was discussed.

Journal

Crystallography Reports – Springer Journals

Published: Jan 25, 2020

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