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Synthesis and structural characterization of a Cu(I) complex with 4-(1 H -imidazol-1-yl)phenyl)methanone ligands

Synthesis and structural characterization of a Cu(I) complex with 4-(1 H... Abstract A copper complex with V-shaped ligands, [(L1)Cu2Cl2] n (1), (L1 = 4-(1H-imidazol-1-yl)phenyl) methanone) has been synthesized and characterized by IR spectroscopy, elemental analyses and singlecrystal X-ray diffraction. The crystal of 1 is monoclinic, sp. gr. C2/c with the unit cell parameters a = 17.9496(13), b = 15.3440(13), c = 7.2983(7) Å, and β = 112.875(6)°, Z = 4, R1 = 0.0681, and wR2 = 0.1736 (I > 2 σ). The solid state structure of 1 consists of 2D metal aromatic chloride layers, which are propagating along the bc plane to form a 3D network through hydrogen bonds. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Crystallography Reports Springer Journals

Synthesis and structural characterization of a Cu(I) complex with 4-(1 H -imidazol-1-yl)phenyl)methanone ligands

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References (23)

Publisher
Springer Journals
Copyright
2017 Pleiades Publishing, Inc.
ISSN
1063-7745
eISSN
1562-689X
DOI
10.1134/S1063774517060268
Publisher site
See Article on Publisher Site

Abstract

Abstract A copper complex with V-shaped ligands, [(L1)Cu2Cl2] n (1), (L1 = 4-(1H-imidazol-1-yl)phenyl) methanone) has been synthesized and characterized by IR spectroscopy, elemental analyses and singlecrystal X-ray diffraction. The crystal of 1 is monoclinic, sp. gr. C2/c with the unit cell parameters a = 17.9496(13), b = 15.3440(13), c = 7.2983(7) Å, and β = 112.875(6)°, Z = 4, R1 = 0.0681, and wR2 = 0.1736 (I > 2 σ). The solid state structure of 1 consists of 2D metal aromatic chloride layers, which are propagating along the bc plane to form a 3D network through hydrogen bonds.

Journal

Crystallography ReportsSpringer Journals

Published: Nov 1, 2017

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