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- Publisher
- Springer Journals
- Copyright
- 2014 Pleiades Publishing, Inc.
- ISSN
- 1063-7745
- eISSN
- 1562-689X
- DOI
- 10.1134/s1063774514020230
- Publisher site
- See Article on Publisher Site
Abstract
Abstract A new complex phosphate Li5Cu2Al(PO4)4 has been obtained by the flux method in the Cs-Li-Cu-V-P-O system. Its crystal structure has been determined by X-ray diffraction (R 1 = 2.74%) to be as follows: sp. gr. \(P\bar 1\), a = 4.860(5) Å, b = 7.788(5) Å, c = 8.324(5) Å, α = 69.542(5)°, β = 90.016(5)°, γ = 75.318(5)°, Z = 1, and V = 284.2(4) Å3. The compound under study has a dense structure and a three-dimensional framework build up of [LiO5], [AlO6], [Cu/LiO5], and [CuO4] polyhedra and [PO4] tetrahedra. A comparative crystal-chemical analysis of two isotypic compounds with a general formula Li5Cu2 M(PO4)4 (M = Fe, Al) has been performed. Topological relations between the Na2Mg5(PO4)4 and Li5Cu2 M(PO4)4 crystal structures, which are characterized by different cationic compositions, are revealed.
Journal
Crystallography Reports – Springer Journals
Published: Mar 1, 2014
Keywords: Crystallography and Scattering Methods