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References (5)
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Crystal and molecular structure of uranyl acetate dihydrateJournal of Inorganic and Nuclear Chemistry, 37
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Zh. Akhmerkina, A. Virovets, E. Peresypkina, L. Serezhkina (2006)
(NH4)(CN3H6)2[UO2(C2O4)2(NCS)] · 2H2O: Synthesis and crystal structureRussian Journal of Inorganic Chemistry, 51
- Publisher
- Springer Journals
- Copyright
- 2010 Pleiades Publishing, Ltd.
- ISSN
- 1063-7745
- eISSN
- 1562-689X
- DOI
- 10.1134/s1063774510010050
- Publisher site
- See Article on Publisher Site
Abstract
Abstract Single crystals of the compound (NH4)3[UO2(CH3COO)3]2[UO2(CH3COO)(NCS)2(H2O)] (I) are synthesized, and their structure is investigated using X-ray diffraction. Compound I crystallizes in the monoclinic system with the unit cell parameters a = 18.3414(6) Å, b = 16.3858(7) Å, c = 12.4183(5) Å, β = 92.992(1)°, space group C2/c, Z = 4, V = 3727.1(3) Å3, and R = 0.0253. The uranium-containing structural units of crystals I are mononuclear complexes of two types with an island structure, i.e., the [UO2(CH3COO)3]− anionic complexes belonging to the crystal-chemical group (AB 013 = UO 2+2 , B 01 = CH3COO−) of the uranyl complexes and the [UO2(CH3COO)(NCS)2(H2O)]− anionic complexes belonging to the crystal-chemical group AB 01M 13 (A = UO 2+2 , B 01 = CH3COO−, M 1 = NCS− or H2O).
Journal
Crystallography Reports – Springer Journals
Published: Jan 1, 2010
Keywords: Crystallography and Scattering Methods