Get 20M+ Full-Text Papers For Less Than $1.50/day. Start a 14-Day Trial for You or Your Team.

Learn More →

Synthesis and crystal structure of Li 3.17 (P 0.69 Ge 0.24 Mo 0.07 )O 4

Synthesis and crystal structure of Li 3.17 (P 0.69 Ge 0.24 Mo 0.07 )O 4 Abstract The crystal structure of Li3.17(P0.69Ge0.24Mo0.07)O4, which was synthesized by the flux method under the action of an electric field with a potential difference of 0.8 V, was studied by X-ray diffraction on a Nonius Kappa CCD diffractometer (MoK α radiation, λ = 0.71073 Å, R = 0.0137). The crystal structure is based on a tetrahedral framework typical of γ-Li3PO4. The framework of the new compound is formed by (P,Ge,Mo)O4 and LiO4 tetrahedra. The positions of additional Li atoms in the structure of Li3.17(P0.69Ge0.24Mo0.07)O4 are found to be different from those in the structure of Li3.31(P0.69Ge0.31)O4, which is synthesized in the absence of an electric field and also belongs to the γ-Li3PO4 structure type. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Crystallography Reports Springer Journals

Synthesis and crystal structure of Li 3.17 (P 0.69 Ge 0.24 Mo 0.07 )O 4

Loading next page...
 
/lp/springer-journals/synthesis-and-crystal-structure-of-li-3-17-p-0-69-ge-0-24-mo-0-07-o-4-07DyQhUysL

References (8)

Publisher
Springer Journals
Copyright
2006 Pleiades Publishing, Inc.
ISSN
1063-7745
eISSN
1562-689X
DOI
10.1134/s1063774506030059
Publisher site
See Article on Publisher Site

Abstract

Abstract The crystal structure of Li3.17(P0.69Ge0.24Mo0.07)O4, which was synthesized by the flux method under the action of an electric field with a potential difference of 0.8 V, was studied by X-ray diffraction on a Nonius Kappa CCD diffractometer (MoK α radiation, λ = 0.71073 Å, R = 0.0137). The crystal structure is based on a tetrahedral framework typical of γ-Li3PO4. The framework of the new compound is formed by (P,Ge,Mo)O4 and LiO4 tetrahedra. The positions of additional Li atoms in the structure of Li3.17(P0.69Ge0.24Mo0.07)O4 are found to be different from those in the structure of Li3.31(P0.69Ge0.31)O4, which is synthesized in the absence of an electric field and also belongs to the γ-Li3PO4 structure type.

Journal

Crystallography ReportsSpringer Journals

Published: May 1, 2006

Keywords: Crystallography and Scattering Methods

There are no references for this article.