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Synthesis and crystal structure of a two-dimensional silver(I)-hexamethylenetetramine coordination polymer ( hmt )

Synthesis and crystal structure of a two-dimensional silver(I)-hexamethylenetetramine... Abstract A novel two-dimensional coordination polymer [Ag(µ3-hexamethylenetetramine)(H2O)](BF4) was synthesized and characterized by X-ray crystallography. It crystallized in the orthorhombic space group Pnnm with a = 15.561(7) Å, b = 10.754(5) Å, c = 6.514(3) Å, and Z = 4. Each Ag center is four-coordinated in a slightly distorted tetrahedral geometry. The structure consists of 2D wavy layers of hexagonal units; these 2D layers are further connected to form a 3D network by O-H⋯F, C-H⋯F hydrogen bonds with counter anions BF −4 in the layers. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Crystallography Reports Springer Journals

Synthesis and crystal structure of a two-dimensional silver(I)-hexamethylenetetramine coordination polymer ( hmt )

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References (17)

Publisher
Springer Journals
Copyright
2005 Pleiades Publishing, Inc.
ISSN
1063-7745
eISSN
1562-689X
DOI
10.1134/1.1996732
Publisher site
See Article on Publisher Site

Abstract

Abstract A novel two-dimensional coordination polymer [Ag(µ3-hexamethylenetetramine)(H2O)](BF4) was synthesized and characterized by X-ray crystallography. It crystallized in the orthorhombic space group Pnnm with a = 15.561(7) Å, b = 10.754(5) Å, c = 6.514(3) Å, and Z = 4. Each Ag center is four-coordinated in a slightly distorted tetrahedral geometry. The structure consists of 2D wavy layers of hexagonal units; these 2D layers are further connected to form a 3D network by O-H⋯F, C-H⋯F hydrogen bonds with counter anions BF −4 in the layers.

Journal

Crystallography ReportsSpringer Journals

Published: Jul 1, 2005

Keywords: Crystallography and Scattering Methods

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