Get 20M+ Full-Text Papers For Less Than $1.50/day. Start a 14-Day Trial for You or Your Team.

Learn More →

Synthesis and characterization of substituted garnet and perovskite-based lithium-ion conducting solid electrolytes

Synthesis and characterization of substituted garnet and perovskite-based lithium-ion conducting... Titanium, tantalum-substituted Li7La3Zr2-xAxO12 (LLZO, A = Ta, Ti) garnets, and chromium-substituted La(2/3)-xLi3xTi1-yCryO3 (LLTO) perovskites were prepared by a conventional solid-state reaction and the Pechini processes. The desired crystal phases were obtained by varying the calcination temperature and time, as well as the substitution concentration. All samples indicated decomposition of the precursors when heated above 750 °C and formation of the desired phase after heat treatment at higher temperatures. Neutron diffraction data shows the formation of a predominant cubic phase in the case of Ta-LLZO, and monoclinic phase with minor impurity phases for Cr-LLTO. Ionic conductivity for Ti-LLZO (Li7La3Zr1.4Ti0.6O12), Ta-LLZO (Li6.03La3Zr1.533Ta0.46O12), and Cr-LLTO (La(2/3)-xLi3xTi0.9Cr0.1O3) at room temperature were found to be 5.21 × 10−6, 1.01 × 10−6, and 1.2 × 10−4 S cm−1, respectively. The activation energies of the compounds were determined from the Arrhenius plot and were 0.44 eV (Ti0.6-LLZO), 0.54 eV (Ta0.5-LLZO), and 0.20 eV (Cr0.1-LLTO). http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Ionics Springer Journals

Synthesis and characterization of substituted garnet and perovskite-based lithium-ion conducting solid electrolytes

Loading next page...
 
/lp/springer-journals/synthesis-and-characterization-of-substituted-garnet-and-perovskite-yMzDKJZZgw

References (26)

Publisher
Springer Journals
Copyright
Copyright © 2015 by Springer-Verlag Berlin Heidelberg (outside the USA)
Subject
Chemistry; Electrochemistry; Renewable and Green Energy; Optical and Electronic Materials; Condensed Matter Physics; Energy Storage
ISSN
0947-7047
eISSN
1862-0760
DOI
10.1007/s11581-015-1556-2
Publisher site
See Article on Publisher Site

Abstract

Titanium, tantalum-substituted Li7La3Zr2-xAxO12 (LLZO, A = Ta, Ti) garnets, and chromium-substituted La(2/3)-xLi3xTi1-yCryO3 (LLTO) perovskites were prepared by a conventional solid-state reaction and the Pechini processes. The desired crystal phases were obtained by varying the calcination temperature and time, as well as the substitution concentration. All samples indicated decomposition of the precursors when heated above 750 °C and formation of the desired phase after heat treatment at higher temperatures. Neutron diffraction data shows the formation of a predominant cubic phase in the case of Ta-LLZO, and monoclinic phase with minor impurity phases for Cr-LLTO. Ionic conductivity for Ti-LLZO (Li7La3Zr1.4Ti0.6O12), Ta-LLZO (Li6.03La3Zr1.533Ta0.46O12), and Cr-LLTO (La(2/3)-xLi3xTi0.9Cr0.1O3) at room temperature were found to be 5.21 × 10−6, 1.01 × 10−6, and 1.2 × 10−4 S cm−1, respectively. The activation energies of the compounds were determined from the Arrhenius plot and were 0.44 eV (Ti0.6-LLZO), 0.54 eV (Ta0.5-LLZO), and 0.20 eV (Cr0.1-LLTO).

Journal

IonicsSpringer Journals

Published: Sep 30, 2015

There are no references for this article.