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R. Lokhande, P. Singare, P. Karthikeyan (2007)
The kinetics and mechanism of bromide ion isotope exchange reaction in strongly basic anion-exchange resin duolite A-162 determined by the radioactive tracer techniqueRussian Journal of Physical Chemistry A, 81
C. Simister, F. Caron, R. Gedye (2004)
Determination of the thermal degradation rate of polystyrene-divinyl benzene ion exchange resins in ultra-pure water at ambient and service temperatureJournal of Radioanalytical and Nuclear Chemistry, 261
C. Buscher, R. Donohoe, S. Mecklenburg, John Berg, C. Tait, K. Huchton, David Morris (1999)
Raman Spectroscopic Study of the Aging and Nitration of Actinide Processing Anion-Exchange Resins in Concentrated Nitric AcidApplied Spectroscopy, 53
R. Lokhande, P. Singare, S. Parab (2008)
Application of radioactive tracer technique to study the kinetics of iodide ion-isotope exchange with strongly basic anion-exchange resin Duolite A-116Radiochemistry, 50
T. Ichikawa, Zenji Hagiwara (1973)
Effect of Gamma-Irradiation on Cation Exchange ResinJournal of Nuclear Science and Technology, 10
(2012)
Sood DD, Reddy AVR, Iyer SRK, Gangadharan S, Singh G (eds) Proc
Matsuda Masami, Funabashi Kiyomi, H. Yusa, M. Kikuchi (1987)
Influence of Functional Sulfonic Acid Group on Pyrolysis Characteristics for Cation Exchange ResinJournal of Nuclear Science and Technology, 24
Xueju Lv, Yiming Xu, K. Lv, Gencheng Zhang (2005)
Photo-assisted degradation of anionic and cationic dyes over iron(III)-loaded resin in the presence of hydrogen peroxideJournal of Photochemistry and Photobiology A-chemistry, 173
R. Lokhande, P. Singare, A. Kolte (2007)
Study on kinetics and mechanism of ion-isotopic exchange reaction using strongly basic anion exchange resins Duolite A 101D and Duolite A 102DRadiochimica Acta, 95
R. Lokhande, P. Singare, S. Tiwari (2009)
Application of Br-82 as a radioactive tracer isotope to study bromide ion-isotopic exchange reaction in strongly basic anion exchange resin Duolite A-161Russian Journal of Physical Chemistry A, 83
R. Lokhande, P. Singare, A. Kolte (2010)
Application of radioactive tracer technique for characterization of strongly basic anion-exchange resins duolite A 101D and duolite A 102D1Radiochemistry, 52
S. Adachi, T. Mizuno, R. Matsuno (1996)
Temperature Dependence of the Distribution Coefficient of Maltooligosaccharides on Cation-exchange Resin in Na(+) Form.Bioscience, biotechnology, and biochemistry, 60 2
P. Tulupov, N. Polyanskii (1973)
Thermal Stability of Anion-exchange ResinsRussian Chemical Reviews, 42
K. Heumann, K. Baier (1982)
Chloride distribution coefficient on strongly basic anion-exchange resin: Dependence on co-ion in alkali fluoride solutionsChromatographia, 15
Z. Gönder, Y. Kaya, I. Vergili, H. Barlas (2006)
Capacity loss in an organically fouled anion exchangerDesalination, 189
R. Lokhande, P. Singare, M. Dole (2006)
Comparative Study on Bromide and Iodide Ion-Isotopic Exchange Reactions Using Strongly Basic Anion Exchange Resin Duolite A-113Journal of nuclear and radiochemical sciences, 7
(2005)
Icemenerg , Bucharest
Matsuda Masami, Funabashi Kiyomi, F. Kawamura, S. Uchida, K. Ohsumi (1987)
Application of Carboxylic Acid Cation Exchange Resin to Water Purification in Nuclear Power PlantsNuclear Technology, 78
(2002)
Application of ion exchange processes for the treatment of radioactive waste and management of spent ion exchangers, technical report series no.408
Monika Zahorodna, R. Bogoczek, E. Oliveros, A. Braun (2007)
Application of the Fenton process to the dissolution and mineralization of ion exchange resinsCatalysis Today, 129
J. Mcconnell, D. Johnson, R. Sanders (1993)
Radiation degradation in organic ion exchange resinsWaste Management, 13
I. Contineanu, Loredana Chivu, S. Perişanu (2005)
The enthalpies of combustion and formation of L-α-glutamic and 6-aminohexanoic acidsJournal of Thermal Analysis and Calorimetry, 82
L. Loon, W. Hummel (1999)
The degradation of strong basic anion exchange resins and mixed-bed ion-exchange resins: Effect of degradation products on radionuclide speciationNuclear Technology, 128
Y. Iwai, T. Yamanishi, A. Hiroki, M. Tamada (2009)
Radiation-Induced Degradation in Ion Exchange Resins for a Water Detritiation SystemFusion Science and Technology, 56
R. Lokhande, P. Singare, M. Dole (2007)
Application of radiotracer technique to study the ion-isotope exchange reactions using a strongly basic anion-exchange resin duolite A-113Radiochemistry, 49
R. Shannon (1976)
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenidesActa Crystallographica Section A, 32
D. Chambree, Cornelia Idioiu, E. Segal, A. Ces´ro (2005)
The study of non-isothermal degradation of acrylic ion-exchange resinsJournal of Thermal Analysis and Calorimetry, 82
S. Adachi, T. Mizuno, R. Matsuno (1995)
Concentration dependence of the distribution coefficient of maltooligosaccharides on a cation-exchange resinJournal of Chromatography A, 708
The present paper deals with the study of iodide and bromide ion-isotopic exchange reactions by application of radioactive tracer technique. The specific reaction rate (per minute) of both the reactions decreases with rise in temperature and increases with concentration of ionic solution. It was observed that due to solvation effect, the iodide ion-isotopic exchange reaction take place at a faster rate than bromide ion-isotopic exchange reaction. Also for iodide ion-isotopic exchange reaction, the distribution coefficient (K d ) values were higher than that for bromide ion-isotopic exchange reaction. The application of tracer technique was further extended for characterization of two widely used nuclear grade ion exchange resins Tulsion A-33 and Duolite ARA 9366. It was observed that the values of K d, specific reaction rate (per minute), amount of ion exchanged (millimoles), and percentage of ions exchanged for Tulsion A-33 resins are higher than that for Duolite ARA 9366 resins under identical experimental conditions.
Ionics – Springer Journals
Published: Nov 15, 2011
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