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We present the vibrational properties of manganese dioxides and lithiated oxides with either spinel-type and layered-type structure used as positive electrodes in Li-ion batteries. The local structure in γ-MnO2 is investigated as a function of the intergrowth rate, Pr, of pyrolusite in the ramsdellite matrix and the phase evolution as a function of the degree of intercalation or deintercalation in 4-volt electrode materials Li1−xCoO2 and Li1−xMn2O4. Lattice dynamics are studied using either a classical group theoretical analysis or a local environment model. Raman and FTIR bands are identified on the basis of vibrational modes of polyhedral units which are building the structure. Structural modifications induced by intercalation-deintercalation process are examined.
Ionics – Springer Journals
Published: Mar 22, 2006
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