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Doklady Chemistt3.; Vol. 375, Nos. 1-3, 2000, pp. 236-241. Translated from Dokla@ Akademii Nauk, Vol. 375, No. 2, 2000, pp. 195-200. Original Russian Text Copyright 9 2000 by Ivanov, Forsling, Kritikos, Antsutkin, Larsen, Zhukov, Yusupov. CHEMISTRY Structural Organization of Zinc, Nickel(II), and Copper(II) O,O'-Dicyclohexyl Phosphorodithioate Complexes as Probed by X-Ray Diffraction, EPR, and Solid-State High-Resolution 13C and 31p NMR A. V. lvanov*, W. Forsling**, M. Kritikos***, O. N. Anzutkin**, A.-C. Larsson**, F. A. Zhukov****, and Z. F. Yusupov**** Presented by Academician I.I. Moiseev July 20, 2000 Received June 7, 2000 An important field for the practical application of nuclear structures, respectively. The 31p NMR signals hydrogen O,O'-dialkyl phosphorodithioate derivatives were assigned to the ligands performing different struc- is their use as selective collecting reagents for the flota- tural functions (i.e., bridging or terminal); in addition, tion of sulfide ores of nonferrous metals. The coordina- the copper(II) coordination polyhedron in the corre- tion compounds of transition metals with these ligands sponding magnetically diluted complexes was found to (Dtph) are used in agriculture as fungicides; they also be nonplanar. function as antioxidants and corrosion inhibitors. These The samples of the [Ni{S2P(O-c-Hex)2}2] (com- complexes can be mono-, bi-, or polynuclear, which is
Doklady Chemistry – Springer Journals
Published: Dec 14, 2007
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