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Stereoelectronic Structure and Alternating Intramolecular Coordination O → Si in N-(Trifluorosilylmethyl)succinimide

Stereoelectronic Structure and Alternating Intramolecular Coordination O → Si in... Doklady Chemistry, Vol. 402, Part 1, 2005, pp. 77–80. Translated from Doklady Akademii Nauk, Vol. 402, No. 3, 2005, pp. 344–347. Original Russian Text Copyright © 2005 by Voronkov, Zel’bst, Katkevich, Kashaev, Fundamenskii, Bolgova, Trofimova, Chernov, Albanov, Baukov, Pestunovich. CHEMISTRY Stereoelectronic Structure and Alternating Intramolecular Coordination O Si in N-(Trifluorosilylmethyl)succinimide Academician M. G. Voronkov, E. A. Zel’bst, Yu. V. Katkevich, A. A. Kashaev, V. S. Fundamenskii, Yu. I. Bolgova, O. M. Trofimova, N. F. Chernov, A. I. Albanov, Yu. I. Baukov, and V. A. Pestunovich Received October 28, 2004 Previously, we studied the crystal and molecular finding out whether this effect is related to the aromatic structures of a new representative of dragonoids [1], character of the five-membered imide heterocycle. For N-(trifluorosilylmethyl)phthalimide (TFSP) [2, 3]. It this purpose, we synthesized previously unknown was found that the TFSP molecule contains a weak N-(trifluorosilylmethyl)succinimide (TFSS), which intramolecular donor–acceptor O Si bond with a contains a saturated five-membered imide heterocycle. length of 2.654 Å (the sum of the van der Waals radii of The compound structure was studied by X-ray diffrac- the Si and O atoms is 3.62 Å). The presence in the mol- tion and multinuclear NMR; the bridge-flipping effect ecule http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Doklady Chemistry Springer Journals

Stereoelectronic Structure and Alternating Intramolecular Coordination O → Si in N-(Trifluorosilylmethyl)succinimide

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References (7)

Publisher
Springer Journals
Copyright
Copyright © 2005 by MAIK “Nauka/Interperiodica”
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
0012-5008
eISSN
1608-3113
DOI
10.1007/s10631-005-0038-x
Publisher site
See Article on Publisher Site

Abstract

Doklady Chemistry, Vol. 402, Part 1, 2005, pp. 77–80. Translated from Doklady Akademii Nauk, Vol. 402, No. 3, 2005, pp. 344–347. Original Russian Text Copyright © 2005 by Voronkov, Zel’bst, Katkevich, Kashaev, Fundamenskii, Bolgova, Trofimova, Chernov, Albanov, Baukov, Pestunovich. CHEMISTRY Stereoelectronic Structure and Alternating Intramolecular Coordination O Si in N-(Trifluorosilylmethyl)succinimide Academician M. G. Voronkov, E. A. Zel’bst, Yu. V. Katkevich, A. A. Kashaev, V. S. Fundamenskii, Yu. I. Bolgova, O. M. Trofimova, N. F. Chernov, A. I. Albanov, Yu. I. Baukov, and V. A. Pestunovich Received October 28, 2004 Previously, we studied the crystal and molecular finding out whether this effect is related to the aromatic structures of a new representative of dragonoids [1], character of the five-membered imide heterocycle. For N-(trifluorosilylmethyl)phthalimide (TFSP) [2, 3]. It this purpose, we synthesized previously unknown was found that the TFSP molecule contains a weak N-(trifluorosilylmethyl)succinimide (TFSS), which intramolecular donor–acceptor O Si bond with a contains a saturated five-membered imide heterocycle. length of 2.654 Å (the sum of the van der Waals radii of The compound structure was studied by X-ray diffrac- the Si and O atoms is 3.62 Å). The presence in the mol- tion and multinuclear NMR; the bridge-flipping effect ecule

Journal

Doklady ChemistrySpringer Journals

Published: Jun 3, 2005

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