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Single-crystal structure of vanadium-doped Nd 5 Mo 3 O 16

Single-crystal structure of vanadium-doped Nd 5 Mo 3 O 16 Abstract The single-crystal structures of the oxygen-ion-conducting fluorite-type compounds Nd5Mo2.90V0.10O15.3 and Nd5Mo2.76V0.24O15.5 were determined by X-ray diffraction. It was found that the displacements of atoms in the structure are retained after the doping of these compounds with vanadium. The dopant atoms occupy the molybdenum sites. The X-ray diffraction data were used to calculate the activation energies and analyze the possible pathways for the oxygen ion migration in the structures. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Crystallography Reports Springer Journals

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References (16)

Publisher
Springer Journals
Copyright
2014 Pleiades Publishing, Inc.
ISSN
1063-7745
eISSN
1562-689X
DOI
10.1134/s1063774514020047
Publisher site
See Article on Publisher Site

Abstract

Abstract The single-crystal structures of the oxygen-ion-conducting fluorite-type compounds Nd5Mo2.90V0.10O15.3 and Nd5Mo2.76V0.24O15.5 were determined by X-ray diffraction. It was found that the displacements of atoms in the structure are retained after the doping of these compounds with vanadium. The dopant atoms occupy the molybdenum sites. The X-ray diffraction data were used to calculate the activation energies and analyze the possible pathways for the oxygen ion migration in the structures.

Journal

Crystallography ReportsSpringer Journals

Published: Mar 1, 2014

Keywords: Crystallography and Scattering Methods

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