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Simulation of prefactor anomalies in superionic conductors in the case of arbitrary energy losses. II. Energy distributions in the barrier region

Simulation of prefactor anomalies in superionic conductors in the case of arbitrary energy... In the framework of Kramers’ rate theory, numerical determination of the distribution of energies is considered for protons transferred in perovskite-like oxides. By referring to the calculational procedures developed in the preceding paper (Samgin and Ezin, Ionics 14: 345–348, 2008), we find that, in many cases, depending upon the value of the energy loss parameter, the distribution in the barrier region is essentially other than the traditional Boltzmann’s distribution. The numerically simulated distributions are briefly analyzed to highlight the collectiveness of the proton transfer mechanism. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Ionics Springer Journals

Simulation of prefactor anomalies in superionic conductors in the case of arbitrary energy losses. II. Energy distributions in the barrier region

Ionics , Volume 15 (6) – Feb 12, 2009

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References (31)

Publisher
Springer Journals
Copyright
Copyright © 2009 by Springer-Verlag
Subject
Chemistry; Condensed Matter Physics; Optical and Electronic Materials; Renewable and Green Energy; Electrochemistry
ISSN
0947-7047
eISSN
1862-0760
DOI
10.1007/s11581-009-0322-8
Publisher site
See Article on Publisher Site

Abstract

In the framework of Kramers’ rate theory, numerical determination of the distribution of energies is considered for protons transferred in perovskite-like oxides. By referring to the calculational procedures developed in the preceding paper (Samgin and Ezin, Ionics 14: 345–348, 2008), we find that, in many cases, depending upon the value of the energy loss parameter, the distribution in the barrier region is essentially other than the traditional Boltzmann’s distribution. The numerically simulated distributions are briefly analyzed to highlight the collectiveness of the proton transfer mechanism.

Journal

IonicsSpringer Journals

Published: Feb 12, 2009

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