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Review on the roles of carbon materials in lead-carbon batteries

Review on the roles of carbon materials in lead-carbon batteries Lead-acid battery (LAB) has been in widespread use for many years due to its mature technology, abound raw materials, low cost, high safety, and high efficiency of recycling. However, the irreversible sulfation in the negative electrode becomes one of the key issues for its further development and application. Lead-carbon battery (LCB) is evolved from LAB by adding different kinds of carbon materials in the negative electrode, and it has effectively suppressed the problem of negative irreversible sulfation of traditional LAB. Different carbon materials play different roles in LCB, including construction of conductive network, double-layer capacitance storage effect, formation of porous structure and steric effect. Moreover, research on composite material additives (such as Pb-C composite materials and polymer-C composite materials) and Pb-C composite electrode have become a research focus in the past few years; it has been another effective way to improve the performance of the negative electrode. On the other hand, due to the relatively low overpotential of carbon materials, the hydrogen evolution reaction (HER) will be aggravated in LCB, which affects its electrochemical performance. It is necessary to modify carbon additives or add other additives to inhibit the HER. This paper will attempt to summarize the roles of carbon additives in the negative electrode made by previous research and illustrate the effect of composite material additives and Pb-C composite electrode on the negative electrode. Moreover, we will also sum up the method for solving the HER by reviewing previous research. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Ionics Springer Journals

Review on the roles of carbon materials in lead-carbon batteries

Ionics , Volume 24 (4) – Feb 1, 2018

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References (104)

Publisher
Springer Journals
Copyright
Copyright © 2018 by Springer-Verlag GmbH Germany, part of Springer Nature
Subject
Chemistry; Electrochemistry; Renewable and Green Energy; Optical and Electronic Materials; Condensed Matter Physics; Energy Storage
ISSN
0947-7047
eISSN
1862-0760
DOI
10.1007/s11581-018-2450-5
Publisher site
See Article on Publisher Site

Abstract

Lead-acid battery (LAB) has been in widespread use for many years due to its mature technology, abound raw materials, low cost, high safety, and high efficiency of recycling. However, the irreversible sulfation in the negative electrode becomes one of the key issues for its further development and application. Lead-carbon battery (LCB) is evolved from LAB by adding different kinds of carbon materials in the negative electrode, and it has effectively suppressed the problem of negative irreversible sulfation of traditional LAB. Different carbon materials play different roles in LCB, including construction of conductive network, double-layer capacitance storage effect, formation of porous structure and steric effect. Moreover, research on composite material additives (such as Pb-C composite materials and polymer-C composite materials) and Pb-C composite electrode have become a research focus in the past few years; it has been another effective way to improve the performance of the negative electrode. On the other hand, due to the relatively low overpotential of carbon materials, the hydrogen evolution reaction (HER) will be aggravated in LCB, which affects its electrochemical performance. It is necessary to modify carbon additives or add other additives to inhibit the HER. This paper will attempt to summarize the roles of carbon additives in the negative electrode made by previous research and illustrate the effect of composite material additives and Pb-C composite electrode on the negative electrode. Moreover, we will also sum up the method for solving the HER by reviewing previous research.

Journal

IonicsSpringer Journals

Published: Feb 1, 2018

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