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Redox isomerization of aromatic nitroso oxides

Redox isomerization of aromatic nitroso oxides ISSN 00125008, Doklady Chemistry, 2012, Vol. 442, Part 1, pp. 12–14. © Pleiades Publishing, Ltd., 2012. Original Russian Text © E.M. Chainikova, R.L. Safiullin, L.V. Spirikhin, 2012, published in Doklady Akademii Nauk, 2012, Vol. 442, No. 2, pp. 200–202. CHEMISTRY E. M. Chainikova, R. L. Safiullin, and L. V. Spirikhin Presented by Academician M.S. Yunusov May 26, 2011 Received June 9, 2011 DOI: 10.1134/S001250081201003X The reaction of triplet aromatic nitrenes with slowly decomposes when exposed to light in an aceto molecular oxygen leads to nitroso oxides ArNOO, nitrile solution at ambient temperature but stable for labile species that are intermediates of photooxidation several weeks upon storage in a freezing chamber. of aromatic azides [1] and deoxygenation of aromatic The UV spectrum of the isolated compound shows nitroso compounds with trivalent phosphorus com a maximum at 300 nm (Fig. 2). The IR spectrum pounds (phosphines and phosphites) in the presence exhibits an intense band in the region of stretching of oxygen [2]. In the course of the photooxidation of –1 1 vibrations of triple bonds (2295 cm ). The H NMR aromatic azides, nitroso oxides are believed to produce spectrum of compound X in CD CN displays four corresponding nitro http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Doklady Chemistry Springer Journals

Redox isomerization of aromatic nitroso oxides

Chainikova, E.; Safiullin, R.; Spirikhin, L.
Doklady Chemistry , Volume 442 (1) – Feb 14, 2012
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References (10)

Publisher
Springer Journals
Copyright
Copyright © 2012 by Pleiades Publishing, Ltd.
Subject
Chemistry; Chemistry/Food Science, general; Industrial Chemistry/Chemical Engineering
ISSN
0012-5008
eISSN
1608-3113
DOI
10.1134/S001250081201003X
Publisher site
See Article on Publisher Site

Abstract

ISSN 00125008, Doklady Chemistry, 2012, Vol. 442, Part 1, pp. 12–14. © Pleiades Publishing, Ltd., 2012. Original Russian Text © E.M. Chainikova, R.L. Safiullin, L.V. Spirikhin, 2012, published in Doklady Akademii Nauk, 2012, Vol. 442, No. 2, pp. 200–202. CHEMISTRY E. M. Chainikova, R. L. Safiullin, and L. V. Spirikhin Presented by Academician M.S. Yunusov May 26, 2011 Received June 9, 2011 DOI: 10.1134/S001250081201003X The reaction of triplet aromatic nitrenes with slowly decomposes when exposed to light in an aceto molecular oxygen leads to nitroso oxides ArNOO, nitrile solution at ambient temperature but stable for labile species that are intermediates of photooxidation several weeks upon storage in a freezing chamber. of aromatic azides [1] and deoxygenation of aromatic The UV spectrum of the isolated compound shows nitroso compounds with trivalent phosphorus com a maximum at 300 nm (Fig. 2). The IR spectrum pounds (phosphines and phosphites) in the presence exhibits an intense band in the region of stretching of oxygen [2]. In the course of the photooxidation of –1 1 vibrations of triple bonds (2295 cm ). The H NMR aromatic azides, nitroso oxides are believed to produce spectrum of compound X in CD CN displays four corresponding nitro

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Doklady Chemistry – Springer Journals

Published: Feb 14, 2012

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