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A.N. Pudovik, I.V. Gur’yanova, E.A. Ishmaeva (1968)
Reaktsii i metody issledovaniya organicheskikh soedinenii
ISSN 0012-5008, Doklady Chemistry, 2006, Vol. 406, Part 2, pp. 15–17. © Pleiades Publishing, Inc., 2006. Original Russian Text © M.B. Gazizov, R.A. Khairullin, A.I. Alekhina, L.R. Bagauva, O.G. Sinyashin, 2006, published in Doklady Akademii Nauk, 2006, Vol. 406, No. 4, pp. 483–485. CHEMISTRY Reaction of 3-(Alkylamino)-2,2-dimethylpropanals with Dialkyl Phosphites M. B. Gazizov, R. A. Khairullin, A. I. Alekhina, L. R. Bagauva, and Corresponding Member of the RAS O. G. Sinyashin Received October 13, 2005 DOI: 10.1134/S0012500806020017 Dialkyl phosphites react with aldehydes in the pres- absence of an additional catalyst since the alkylamino ence of triethylamine as a catalyst to form 1-hydroxy- group of the initial aldehyde II functions as a basic cat- alkylphosphonates [1]. The reaction mixture is heated alyst. When compound II is added dropwise to a dialkyl at 80°C. No information on 3-(alkylamino)-1-hydroxy- phosphite, the temperature of the reaction mixture alkylphosphonates is available. For their synthesis, we increases to 40–50°C. The reaction mixture should be studied a new reaction between dialkyl phosphites I and stirred at 25°C for 24 h for the reaction to complete 3-(alkylamino)-2,2-dimethylpropanals II. (monitored by the disappearance of the H NMR signal The aim of this work was to determine the optimal
Doklady Chemistry – Springer Journals
Published: Mar 21, 2006
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